{2-[(2,6-Difluorophenoxy)methyl]phenyl}boronic acid

{2-[(2,6-Difluorophenoxy)methyl]phenyl}boronic acid

The planes of the two benzene rings in the molecule of the title compound, C13H11BF2O3, form a dihedral angle of 76.06 (3)°; the C—O—C—C torsion angle characterizing the conformation of the central link of the molecule is &...

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Main Authors: Tomasz Klis, Janusz Serwatowski
Format: Article
Language:English
Published: International Union of Crystallography 2009-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809035235
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spelling doaj-3e48ba7c5fe74eaebba7850e867e85b22020-11-25T01:14:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-10-016510o2348o234810.1107/S1600536809035235{2-[(2,6-Difluorophenoxy)methyl]phenyl}boronic acidTomasz KlisJanusz SerwatowskiThe planes of the two benzene rings in the molecule of the title compound, C13H11BF2O3, form a dihedral angle of 76.06 (3)°; the C—O—C—C torsion angle characterizing the conformation of the central link of the molecule is −79.20 (1)°. The dihydroxyboron group is not coplanar with the benzene ring bonded to the B atom; one of the C—C—B—O torsion angles is 32.39 (2)°. One of the OH groups of the boronic acid fragment is engaged in an intramolecular hydrogen bond, whereas the second OH group participates in intermolecular hydrogen bonding, which leads to the formation of centrosymmetric dimers. http://scripts.iucr.org/cgi-bin/paper?S1600536809035235
collection DOAJ
language English
format Article
sources DOAJ
author Tomasz Klis
Janusz Serwatowski
spellingShingle Tomasz Klis
Janusz Serwatowski
{2-[(2,6-Difluorophenoxy)methyl]phenyl}boronic acid
Acta Crystallographica Section E
author_facet Tomasz Klis
Janusz Serwatowski
author_sort Tomasz Klis
title {2-[(2,6-Difluorophenoxy)methyl]phenyl}boronic acid
title_short {2-[(2,6-Difluorophenoxy)methyl]phenyl}boronic acid
title_full {2-[(2,6-Difluorophenoxy)methyl]phenyl}boronic acid
title_fullStr {2-[(2,6-Difluorophenoxy)methyl]phenyl}boronic acid
title_full_unstemmed {2-[(2,6-Difluorophenoxy)methyl]phenyl}boronic acid
title_sort {2-[(2,6-difluorophenoxy)methyl]phenyl}boronic acid
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-10-01
description The planes of the two benzene rings in the molecule of the title compound, C13H11BF2O3, form a dihedral angle of 76.06 (3)°; the C—O—C—C torsion angle characterizing the conformation of the central link of the molecule is −79.20 (1)°. The dihydroxyboron group is not coplanar with the benzene ring bonded to the B atom; one of the C—C—B—O torsion angles is 32.39 (2)°. One of the OH groups of the boronic acid fragment is engaged in an intramolecular hydrogen bond, whereas the second OH group participates in intermolecular hydrogen bonding, which leads to the formation of centrosymmetric dimers.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809035235
work_keys_str_mv AT tomaszklis 226difluorophenoxymethylphenylboronicacid
AT januszserwatowski 226difluorophenoxymethylphenylboronicacid
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