{2-[(2,6-Difluorophenoxy)methyl]phenyl}boronic acid

The planes of the two benzene rings in the molecule of the title compound, C13H11BF2O3, form a dihedral angle of 76.06 (3)°; the C—O—C—C torsion angle characterizing the conformation of the central link of the molecule is &...

Full description

Bibliographic Details
Main Authors: Tomasz Klis, Janusz Serwatowski
Format: Article
Language:English
Published: International Union of Crystallography 2009-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809035235
Description
Summary:The planes of the two benzene rings in the molecule of the title compound, C13H11BF2O3, form a dihedral angle of 76.06 (3)°; the C—O—C—C torsion angle characterizing the conformation of the central link of the molecule is −79.20 (1)°. The dihydroxyboron group is not coplanar with the benzene ring bonded to the B atom; one of the C—C—B—O torsion angles is 32.39 (2)°. One of the OH groups of the boronic acid fragment is engaged in an intramolecular hydrogen bond, whereas the second OH group participates in intermolecular hydrogen bonding, which leads to the formation of centrosymmetric dimers.
ISSN:1600-5368