trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)

trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)

In the centrosymmetric title complex, [Co(C7H4NO3S)2(C6H15N3)2], the CoII ion is coordinated by two saccharinate (sac) anions and two neutral 2-piperazin-1-ylethanamine (ppzea) ligands, showing a distorted octahedral coordination. Sac is O-bonded via the carbonyl group, while ppzea acts as an N,N&am...

Full description

Bibliographic Details
Main Authors: Veysel T. Yilmaz, Serkan Guney, Canan Kazak
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807062745
id doaj-3e413913d1f941ab89a3391d57033e3c
record_format Article
spelling doaj-3e413913d1f941ab89a3391d57033e3c2020-11-24T22:09:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m59m6010.1107/S1600536807062745trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)Veysel T. YilmazSerkan GuneyCanan KazakIn the centrosymmetric title complex, [Co(C7H4NO3S)2(C6H15N3)2], the CoII ion is coordinated by two saccharinate (sac) anions and two neutral 2-piperazin-1-ylethanamine (ppzea) ligands, showing a distorted octahedral coordination. Sac is O-bonded via the carbonyl group, while ppzea acts as an N,N′-bidentate chelating ligand. The molecules are connected by N—H...N and N—H...O hydrogen bonds, forming a linear chain running parallel to the crystallographic a axis. The compound is isostructural with the reported Ni, Zn, and Cd analogues.http://scripts.iucr.org/cgi-bin/paper?S1600536807062745
collection DOAJ
language English
format Article
sources DOAJ
author Veysel T. Yilmaz
Serkan Guney
Canan Kazak
spellingShingle Veysel T. Yilmaz
Serkan Guney
Canan Kazak
trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)
Acta Crystallographica Section E
author_facet Veysel T. Yilmaz
Serkan Guney
Canan Kazak
author_sort Veysel T. Yilmaz
title trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)
title_short trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)
title_full trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)
title_fullStr trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)
title_full_unstemmed trans-Bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(II)
title_sort trans-bis[2-(piperazin-1-yl)ethanamine]bis(saccharinato)cobalt(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-01-01
description In the centrosymmetric title complex, [Co(C7H4NO3S)2(C6H15N3)2], the CoII ion is coordinated by two saccharinate (sac) anions and two neutral 2-piperazin-1-ylethanamine (ppzea) ligands, showing a distorted octahedral coordination. Sac is O-bonded via the carbonyl group, while ppzea acts as an N,N′-bidentate chelating ligand. The molecules are connected by N—H...N and N—H...O hydrogen bonds, forming a linear chain running parallel to the crystallographic a axis. The compound is isostructural with the reported Ni, Zn, and Cd analogues.
url http://scripts.iucr.org/cgi-bin/paper?S1600536807062745
work_keys_str_mv AT veyseltyilmaz transbis2piperazin1ylethanaminebissaccharinatocobaltii
AT serkanguney transbis2piperazin1ylethanaminebissaccharinatocobaltii
AT canankazak transbis2piperazin1ylethanaminebissaccharinatocobaltii
_version_ 1725812103652048896

Similar Items