1d-1-O-tert-Butyldiphenylsilyl-2,3,6-O-tris(methoxymethylene)-myo-inositol 4,5-bis(dibenzylphosphate)

1d-1-O-tert-Butyldiphenylsilyl-2,3,6-O-tris(methoxymethylene)-myo-inositol 4,5-bis(dibenzylphosphate)

The title compound [systematic name: tetrabenzyl (1R,2R,3S,4R,5R,6S)-4-(tert-butyldiphenylsilyloxy)-3,5,6-tris(methoxymethoxy)cyclohexane-1,2-diyl bisphosphate], C56H68O15P2Si, was isolated as an intermediate in the preparation of a phosphatidylinositol phosphate for biological studies. In the cryst...

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Main Authors: Regan J. Anderson, Graeme J. Gainsford
Format: Article
Language:English
Published: International Union of Crystallography 2012-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812008069
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spelling doaj-3e30b53602e44cefa1c025dff87e911a2020-11-25T01:35:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683o900o90010.1107/S16005368120080691d-1-O-tert-Butyldiphenylsilyl-2,3,6-O-tris(methoxymethylene)-myo-inositol 4,5-bis(dibenzylphosphate)Regan J. AndersonGraeme J. GainsfordThe title compound [systematic name: tetrabenzyl (1R,2R,3S,4R,5R,6S)-4-(tert-butyldiphenylsilyloxy)-3,5,6-tris(methoxymethoxy)cyclohexane-1,2-diyl bisphosphate], C56H68O15P2Si, was isolated as an intermediate in the preparation of a phosphatidylinositol phosphate for biological studies. In the crystal, the molecules are connected via one methylene C—H...π and two weak phenyl–ether C—H...O interactions. One benzyloxy group is disordered over two overlapping positions with an occupancy ratio of 0.649 (7):0.351 (7).http://scripts.iucr.org/cgi-bin/paper?S1600536812008069
collection DOAJ
language English
format Article
sources DOAJ
author Regan J. Anderson
Graeme J. Gainsford
spellingShingle Regan J. Anderson
Graeme J. Gainsford
1d-1-O-tert-Butyldiphenylsilyl-2,3,6-O-tris(methoxymethylene)-myo-inositol 4,5-bis(dibenzylphosphate)
Acta Crystallographica Section E
author_facet Regan J. Anderson
Graeme J. Gainsford
author_sort Regan J. Anderson
title 1d-1-O-tert-Butyldiphenylsilyl-2,3,6-O-tris(methoxymethylene)-myo-inositol 4,5-bis(dibenzylphosphate)
title_short 1d-1-O-tert-Butyldiphenylsilyl-2,3,6-O-tris(methoxymethylene)-myo-inositol 4,5-bis(dibenzylphosphate)
title_full 1d-1-O-tert-Butyldiphenylsilyl-2,3,6-O-tris(methoxymethylene)-myo-inositol 4,5-bis(dibenzylphosphate)
title_fullStr 1d-1-O-tert-Butyldiphenylsilyl-2,3,6-O-tris(methoxymethylene)-myo-inositol 4,5-bis(dibenzylphosphate)
title_full_unstemmed 1d-1-O-tert-Butyldiphenylsilyl-2,3,6-O-tris(methoxymethylene)-myo-inositol 4,5-bis(dibenzylphosphate)
title_sort 1d-1-o-tert-butyldiphenylsilyl-2,3,6-o-tris(methoxymethylene)-myo-inositol 4,5-bis(dibenzylphosphate)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-03-01
description The title compound [systematic name: tetrabenzyl (1R,2R,3S,4R,5R,6S)-4-(tert-butyldiphenylsilyloxy)-3,5,6-tris(methoxymethoxy)cyclohexane-1,2-diyl bisphosphate], C56H68O15P2Si, was isolated as an intermediate in the preparation of a phosphatidylinositol phosphate for biological studies. In the crystal, the molecules are connected via one methylene C—H...π and two weak phenyl–ether C—H...O interactions. One benzyloxy group is disordered over two overlapping positions with an occupancy ratio of 0.649 (7):0.351 (7).
url http://scripts.iucr.org/cgi-bin/paper?S1600536812008069
work_keys_str_mv AT reganjanderson 1d1otertbutyldiphenylsilyl236otrismethoxymethylenemyoinositol45bisdibenzylphosphate
AT graemejgainsford 1d1otertbutyldiphenylsilyl236otrismethoxymethylenemyoinositol45bisdibenzylphosphate
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