SORPTION-SPECTROPHOTOMETRIC DETERMINATION OF Al (III), Ga (III), In (III) ВY USING DIMETHYLCHLOROSILANEAEROSILE, IMPREGNATING BY POLARITY SOLVENT
The sorption-spectrophotometric determination techniques (metodic) of Al (III), Ga (III), In (III) microquantities has been developed, including previouslyseparation of elements-analogs with the use of dimethylchlorosilaneaerosile (DMCSA), impregnated by polar organic solvent – ethanol or acetone de...
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Odessa I. I. Mechnikov National University
2015-02-01
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doaj-3e2c85cd8d6149e7aa4daafe24748ec02020-11-24T22:33:43ZengOdessa I. I. Mechnikov National University Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ2304-09472414-59632015-02-01191(49)323810.18524/2304-0947.2014.1(49).3831138311SORPTION-SPECTROPHOTOMETRIC DETERMINATION OF Al (III), Ga (III), In (III) ВY USING DIMETHYLCHLOROSILANEAEROSILE, IMPREGNATING BY POLARITY SOLVENTA. N. Chebotarev0E. M. Rakhlytskaya1A. N. Zakhariya2Одеський національний університет імені І. І. Мечникова, кафедра аналітичної хіміїОдеський національний університет імені І. І. Мечникова, кафедра аналітичної хіміїОдеський національний університет імені І. І. Мечникова, кафедра аналітичної хіміїThe sorption-spectrophotometric determination techniques (metodic) of Al (III), Ga (III), In (III) microquantities has been developed, including previouslyseparation of elements-analogs with the use of dimethylchlorosilaneaerosile (DMCSA), impregnated by polar organic solvent – ethanol or acetone depending on pH. The conditions of Ga and In quantitative desorption from DMCSAsurface by using ultrasonic radiationwere optimized. Spectrophotometric determination of Al, Ga, In, located in separate portions of the solution,was carried out with xylenol orange by known methods. The methodicwas tested on circulating waters of alumina production.http://heraldchem.onu.edu.ua/article/view/38311сорбція, алюміній, галій, індій, диметилхлорсиланаеросил, спектрофотометрія |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
A. N. Chebotarev E. M. Rakhlytskaya A. N. Zakhariya |
spellingShingle |
A. N. Chebotarev E. M. Rakhlytskaya A. N. Zakhariya SORPTION-SPECTROPHOTOMETRIC DETERMINATION OF Al (III), Ga (III), In (III) ВY USING DIMETHYLCHLOROSILANEAEROSILE, IMPREGNATING BY POLARITY SOLVENT Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ сорбція, алюміній, галій, індій, диметилхлорсиланаеросил, спектрофотометрія |
author_facet |
A. N. Chebotarev E. M. Rakhlytskaya A. N. Zakhariya |
author_sort |
A. N. Chebotarev |
title |
SORPTION-SPECTROPHOTOMETRIC DETERMINATION OF Al (III), Ga (III), In (III) ВY USING DIMETHYLCHLOROSILANEAEROSILE, IMPREGNATING BY POLARITY SOLVENT |
title_short |
SORPTION-SPECTROPHOTOMETRIC DETERMINATION OF Al (III), Ga (III), In (III) ВY USING DIMETHYLCHLOROSILANEAEROSILE, IMPREGNATING BY POLARITY SOLVENT |
title_full |
SORPTION-SPECTROPHOTOMETRIC DETERMINATION OF Al (III), Ga (III), In (III) ВY USING DIMETHYLCHLOROSILANEAEROSILE, IMPREGNATING BY POLARITY SOLVENT |
title_fullStr |
SORPTION-SPECTROPHOTOMETRIC DETERMINATION OF Al (III), Ga (III), In (III) ВY USING DIMETHYLCHLOROSILANEAEROSILE, IMPREGNATING BY POLARITY SOLVENT |
title_full_unstemmed |
SORPTION-SPECTROPHOTOMETRIC DETERMINATION OF Al (III), Ga (III), In (III) ВY USING DIMETHYLCHLOROSILANEAEROSILE, IMPREGNATING BY POLARITY SOLVENT |
title_sort |
sorption-spectrophotometric determination of al (iii), ga (iii), in (iii) вy using dimethylchlorosilaneaerosile, impregnating by polarity solvent |
publisher |
Odessa I. I. Mechnikov National University |
series |
Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ |
issn |
2304-0947 2414-5963 |
publishDate |
2015-02-01 |
description |
The sorption-spectrophotometric determination techniques (metodic) of Al (III), Ga (III), In (III) microquantities has been developed, including previouslyseparation of elements-analogs with the use of dimethylchlorosilaneaerosile (DMCSA), impregnated by polar organic solvent – ethanol or acetone depending on pH. The conditions of Ga and In quantitative desorption from DMCSAsurface by using ultrasonic radiationwere optimized. Spectrophotometric determination of Al, Ga, In, located in separate portions of the solution,was carried out with xylenol orange by known methods. The methodicwas tested on circulating waters of alumina production. |
topic |
сорбція, алюміній, галій, індій, диметилхлорсиланаеросил, спектрофотометрія |
url |
http://heraldchem.onu.edu.ua/article/view/38311 |
work_keys_str_mv |
AT anchebotarev sorptionspectrophotometricdeterminationofaliiigaiiiiniiivyusingdimethylchlorosilaneaerosileimpregnatingbypolaritysolvent AT emrakhlytskaya sorptionspectrophotometricdeterminationofaliiigaiiiiniiivyusingdimethylchlorosilaneaerosileimpregnatingbypolaritysolvent AT anzakhariya sorptionspectrophotometricdeterminationofaliiigaiiiiniiivyusingdimethylchlorosilaneaerosileimpregnatingbypolaritysolvent |
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1725729740053020672 |