Kinetic modeling of the biosorption of Cd2+ ions from aqueous solutions onto Eichhornia crassipes roots using potentiometry: low-cost alternative to conventional methods

This work presents the use of potentiometric measurements for kinetic studies of biosorption of Cd2+ ions from aqueous solutions on Eichhornia crassipes roots. The open circuit potential of the Cd/Cd2+ electrode of the first kind was measured during the bioadsorption process. The amount of Cd2+ ions...

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Main Authors: Carolina Martínez-Sánchez, Luz María Torres-Rodríguez, Ramón Fernando García de la Cruz
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2013-01-01
Series:Química Nova
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422013000800022&lng=en&tlng=en
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spelling doaj-3de8ebe0b3b0483e87c88b1e9cd921b92020-11-24T23:52:13ZengSociedade Brasileira de QuímicaQuímica Nova1678-70642013-01-013681227123110.1590/S0100-40422013000800022S0100-40422013000800022Kinetic modeling of the biosorption of Cd2+ ions from aqueous solutions onto Eichhornia crassipes roots using potentiometry: low-cost alternative to conventional methodsCarolina Martínez-Sánchez0Luz María Torres-Rodríguez1Ramón Fernando García de la Cruz2Universidad Autónoma de San Luis PotosíUniversidad Autónoma de San Luis PotosíUniversidad Autónoma de San Luis PotosíThis work presents the use of potentiometric measurements for kinetic studies of biosorption of Cd2+ ions from aqueous solutions on Eichhornia crassipes roots. The open circuit potential of the Cd/Cd2+ electrode of the first kind was measured during the bioadsorption process. The amount of Cd2+ ions accumulated was determined in real time. The data were fit to different models, with the pseudo-second-order model proving to be the best in describing the data. The advantages and limitations of the methodology proposed relative to the traditional method are discussed.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422013000800022&lng=en&tlng=enbiosorptionpotentiometrykinetics
collection DOAJ
language English
format Article
sources DOAJ
author Carolina Martínez-Sánchez
Luz María Torres-Rodríguez
Ramón Fernando García de la Cruz
spellingShingle Carolina Martínez-Sánchez
Luz María Torres-Rodríguez
Ramón Fernando García de la Cruz
Kinetic modeling of the biosorption of Cd2+ ions from aqueous solutions onto Eichhornia crassipes roots using potentiometry: low-cost alternative to conventional methods
Química Nova
biosorption
potentiometry
kinetics
author_facet Carolina Martínez-Sánchez
Luz María Torres-Rodríguez
Ramón Fernando García de la Cruz
author_sort Carolina Martínez-Sánchez
title Kinetic modeling of the biosorption of Cd2+ ions from aqueous solutions onto Eichhornia crassipes roots using potentiometry: low-cost alternative to conventional methods
title_short Kinetic modeling of the biosorption of Cd2+ ions from aqueous solutions onto Eichhornia crassipes roots using potentiometry: low-cost alternative to conventional methods
title_full Kinetic modeling of the biosorption of Cd2+ ions from aqueous solutions onto Eichhornia crassipes roots using potentiometry: low-cost alternative to conventional methods
title_fullStr Kinetic modeling of the biosorption of Cd2+ ions from aqueous solutions onto Eichhornia crassipes roots using potentiometry: low-cost alternative to conventional methods
title_full_unstemmed Kinetic modeling of the biosorption of Cd2+ ions from aqueous solutions onto Eichhornia crassipes roots using potentiometry: low-cost alternative to conventional methods
title_sort kinetic modeling of the biosorption of cd2+ ions from aqueous solutions onto eichhornia crassipes roots using potentiometry: low-cost alternative to conventional methods
publisher Sociedade Brasileira de Química
series Química Nova
issn 1678-7064
publishDate 2013-01-01
description This work presents the use of potentiometric measurements for kinetic studies of biosorption of Cd2+ ions from aqueous solutions on Eichhornia crassipes roots. The open circuit potential of the Cd/Cd2+ electrode of the first kind was measured during the bioadsorption process. The amount of Cd2+ ions accumulated was determined in real time. The data were fit to different models, with the pseudo-second-order model proving to be the best in describing the data. The advantages and limitations of the methodology proposed relative to the traditional method are discussed.
topic biosorption
potentiometry
kinetics
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422013000800022&lng=en&tlng=en
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AT luzmariatorresrodriguez kineticmodelingofthebiosorptionofcd2ionsfromaqueoussolutionsontoeichhorniacrassipesrootsusingpotentiometrylowcostalternativetoconventionalmethods
AT ramonfernandogarciadelacruz kineticmodelingofthebiosorptionofcd2ionsfromaqueoussolutionsontoeichhorniacrassipesrootsusingpotentiometrylowcostalternativetoconventionalmethods
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