[2,6-Bis(5-ethoxy-1,3-oxazol-2-yl)-4-methoxyphenyl-κ3N,C1,N′]bromidopalladium(II)

[2,6-Bis(5-ethoxy-1,3-oxazol-2-yl)-4-methoxyphenyl-κ3N,C1,N′]bromidopalladium(II)

In the title compound, [PdBr(C17H17N2O5)], the PdII atom is coordinated by an N,C1,N′-tridentate pincer ligand and a Br atom in a distorted square-planar geometry. In the crystal, molecules are connected by C—H...Br and C—H...O hydrogen bonds, and &#...

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Bibliographic Details
Main Authors: Wen-Hui Nan, Jian-Ping Tan, Qun-Li Luo
Format: Article
Language:English
Published: International Union of Crystallography 2013-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812049197
Description
Summary:In the title compound, [PdBr(C17H17N2O5)], the PdII atom is coordinated by an N,C1,N′-tridentate pincer ligand and a Br atom in a distorted square-planar geometry. In the crystal, molecules are connected by C—H...Br and C—H...O hydrogen bonds, and π–π interactions between the oxazole and benzene rings [centroid–centroid distance = 3.7344 (19) Å], resulting in a three-dimensional supramolecular structure.
ISSN:1600-5368

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