Heptacarbonylbis(μ-propane-1,3-dithiolato)triiron(I,II)(2 Fe—Fe)

The trinuclear title compound, [Fe3(C3H6S2)2(CO)7], is a mixed-valent FeI/FeII complex and crystallizes with two molecules of similar configuration in the asymmetric unit. The three Fe atoms in each molecule display a bent arrangement [Fe—Fe—Fe = 156.22 (4) and 157.06 (3)°]. Both outer FeI atoms are...

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Bibliographic Details
Main Authors: Mingqiang Hu, Chengbing Ma, Huimin Wen, Honghua Cui, Changneng Chen
Format: Article
Language:English
Published: International Union of Crystallography 2014-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814004619