Low Ppm Atom Transfer Radical Polymerization in (Mini)Emulsion Systems

In the last decade, unceasing interest in atom transfer radical polymerization (ATRP) has been noted, especially in aqueous dispersion systems. Emulsion or miniemulsion is a preferred environment for industrial polymerization due to easier heat dissipation and lower production costs associated with...

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Bibliographic Details
Main Authors: Karolina Surmacz, Paweł Chmielarz
Format: Article
Language:English
Published: MDPI AG 2020-04-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/7/1717
Description
Summary:In the last decade, unceasing interest in atom transfer radical polymerization (ATRP) has been noted, especially in aqueous dispersion systems. Emulsion or miniemulsion is a preferred environment for industrial polymerization due to easier heat dissipation and lower production costs associated with the use of water as a dispersant. The main purpose of this review is to summarize ATRP methods used in emulsion media with different variants of initiating systems. A comparison of a dual over single catalytic approache by interfacial and ion pair catalysis is presented. In addition, future development directions for these methods are suggested for better use in biomedical and electronics industries.
ISSN:1996-1944