[N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O2]diphenyltin(IV)

[N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O2]diphenyltin(IV)

The SnIV atom in the title compound, [Sn(C6H5)2(C18H11ClN2O3)], is O,N,O′-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C2SnNO2 trigonal-bipyramidal geometry [C—Sn—C = 125.7 (2)&am...

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Bibliographic Details
Main Authors: Seik Weng Ng, Hapipah Mohd Ali, Kong Mun Lo, See Mun Lee
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809050107
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spelling doaj-3d528e406c8642b8a1a777dfca9b1b8d2020-11-24T21:53:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1689m168910.1107/S1600536809050107[N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O2]diphenyltin(IV)Seik Weng NgHapipah Mohd AliKong Mun LoSee Mun LeeThe SnIV atom in the title compound, [Sn(C6H5)2(C18H11ClN2O3)], is O,N,O′-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C2SnNO2 trigonal-bipyramidal geometry [C—Sn—C = 125.7 (2)°]. The two phenyl rings are oriented at a dihedral angle of 55.2 (3)°. Intramolecular O—H...N hydrogen bonding is present in the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536809050107
collection DOAJ
language English
format Article
sources DOAJ
author Seik Weng Ng
Hapipah Mohd Ali
Kong Mun Lo
See Mun Lee
spellingShingle Seik Weng Ng
Hapipah Mohd Ali
Kong Mun Lo
See Mun Lee
[N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O2]diphenyltin(IV)
Acta Crystallographica Section E
author_facet Seik Weng Ng
Hapipah Mohd Ali
Kong Mun Lo
See Mun Lee
author_sort Seik Weng Ng
title [N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O2]diphenyltin(IV)
title_short [N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O2]diphenyltin(IV)
title_full [N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O2]diphenyltin(IV)
title_fullStr [N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O2]diphenyltin(IV)
title_full_unstemmed [N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O2]diphenyltin(IV)
title_sort [n′-(5-chloro-2-oxidobenzylidene-κo)-3-hydroxy-2-naphthohydrazidato-κ2n′,o2]diphenyltin(iv)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-12-01
description The SnIV atom in the title compound, [Sn(C6H5)2(C18H11ClN2O3)], is O,N,O′-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C2SnNO2 trigonal-bipyramidal geometry [C—Sn—C = 125.7 (2)°]. The two phenyl rings are oriented at a dihedral angle of 55.2 (3)°. Intramolecular O—H...N hydrogen bonding is present in the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809050107
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AT hapipahmohdali namp82425chloro2oxidobenzylideneamp954o3hydroxy2naphthohydrazidatoamp9542namp8242o2diphenyltiniv
AT kongmunlo namp82425chloro2oxidobenzylideneamp954o3hydroxy2naphthohydrazidatoamp9542namp8242o2diphenyltiniv
AT seemunlee namp82425chloro2oxidobenzylideneamp954o3hydroxy2naphthohydrazidatoamp9542namp8242o2diphenyltiniv
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