Iodine-catalyzed diazo activation to access radical reactivity
Radical reactivity of diazo compounds, useful organic building blocks, is yet underexplored. Here, the authors report an iodine-catalyzed radical activation of diazo compounds affording a variety of substituted cyclopropanes, pyrroles and epoxides under either thermal- or photo-initiated conditions.
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| Format: | Article |
| Language: | English |
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Nature Publishing Group
2018-05-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-018-04331-4 |
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doaj-3d4bdc12eafd4435b303af919c20f59c2021-05-11T10:33:22ZengNature Publishing GroupNature Communications2041-17232018-05-01911910.1038/s41467-018-04331-4Iodine-catalyzed diazo activation to access radical reactivityPan Li0Jingjing Zhao1Lijun Shi2Jin Wang3Xiaodong Shi4Fuwei Li5State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of SciencesDepartment of Chemistry, University of South FloridaDepartment of Chemistry, University of South FloridaState Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of SciencesRadical reactivity of diazo compounds, useful organic building blocks, is yet underexplored. Here, the authors report an iodine-catalyzed radical activation of diazo compounds affording a variety of substituted cyclopropanes, pyrroles and epoxides under either thermal- or photo-initiated conditions.https://doi.org/10.1038/s41467-018-04331-4 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Pan Li Jingjing Zhao Lijun Shi Jin Wang Xiaodong Shi Fuwei Li |
| spellingShingle |
Pan Li Jingjing Zhao Lijun Shi Jin Wang Xiaodong Shi Fuwei Li Iodine-catalyzed diazo activation to access radical reactivity Nature Communications |
| author_facet |
Pan Li Jingjing Zhao Lijun Shi Jin Wang Xiaodong Shi Fuwei Li |
| author_sort |
Pan Li |
| title |
Iodine-catalyzed diazo activation to access radical reactivity |
| title_short |
Iodine-catalyzed diazo activation to access radical reactivity |
| title_full |
Iodine-catalyzed diazo activation to access radical reactivity |
| title_fullStr |
Iodine-catalyzed diazo activation to access radical reactivity |
| title_full_unstemmed |
Iodine-catalyzed diazo activation to access radical reactivity |
| title_sort |
iodine-catalyzed diazo activation to access radical reactivity |
| publisher |
Nature Publishing Group |
| series |
Nature Communications |
| issn |
2041-1723 |
| publishDate |
2018-05-01 |
| description |
Radical reactivity of diazo compounds, useful organic building blocks, is yet underexplored. Here, the authors report an iodine-catalyzed radical activation of diazo compounds affording a variety of substituted cyclopropanes, pyrroles and epoxides under either thermal- or photo-initiated conditions. |
| url |
https://doi.org/10.1038/s41467-018-04331-4 |
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| _version_ |
1721447930559201280 |