Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ2N,P}methylpalladium(II) dichloromethane hemisolvate

Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ2N,P}methylpalladium(II) dichloromethane hemisolvate

In the title compound, [Pd(CH3)Cl(C25H22NPS)]·0.5C2H2Cl2, the PdII atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thiophene ring is equally disorde...

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Main Authors: Martin O. Onani, William M. Motswainyana, Emmanuel I. Iwuoha, James Darkwa, Roger A. Lalancette
Format: Article
Language:English
Published: International Union of Crystallography 2010-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810017824
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spelling doaj-3d25740141d7463daff519e6e65512912020-11-24T21:53:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666m688m68810.1107/S1600536810017824Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ2N,P}methylpalladium(II) dichloromethane hemisolvateMartin O. OnaniWilliam M. MotswainyanaEmmanuel I. IwuohaJames DarkwaRoger A. LalancetteIn the title compound, [Pd(CH3)Cl(C25H22NPS)]·0.5C2H2Cl2, the PdII atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thiophene ring is equally disordered over two orientations and the dichloromethane solvent molecule is disordered about an inversion centre. http://scripts.iucr.org/cgi-bin/paper?S1600536810017824
collection DOAJ
language English
format Article
sources DOAJ
author Martin O. Onani
William M. Motswainyana
Emmanuel I. Iwuoha
James Darkwa
Roger A. Lalancette
spellingShingle Martin O. Onani
William M. Motswainyana
Emmanuel I. Iwuoha
James Darkwa
Roger A. Lalancette
Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ2N,P}methylpalladium(II) dichloromethane hemisolvate
Acta Crystallographica Section E
author_facet Martin O. Onani
William M. Motswainyana
Emmanuel I. Iwuoha
James Darkwa
Roger A. Lalancette
author_sort Martin O. Onani
title Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ2N,P}methylpalladium(II) dichloromethane hemisolvate
title_short Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ2N,P}methylpalladium(II) dichloromethane hemisolvate
title_full Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ2N,P}methylpalladium(II) dichloromethane hemisolvate
title_fullStr Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ2N,P}methylpalladium(II) dichloromethane hemisolvate
title_full_unstemmed Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ2N,P}methylpalladium(II) dichloromethane hemisolvate
title_sort chlorido{n-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ2n,p}methylpalladium(ii) dichloromethane hemisolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-06-01
description In the title compound, [Pd(CH3)Cl(C25H22NPS)]·0.5C2H2Cl2, the PdII atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thiophene ring is equally disordered over two orientations and the dichloromethane solvent molecule is disordered about an inversion centre.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810017824
work_keys_str_mv AT martinoonani chloridon2diphenylphosphanylbenzylidene22thienylethanamineamp9542npmethylpalladiumiidichloromethanehemisolvate
AT williammmotswainyana chloridon2diphenylphosphanylbenzylidene22thienylethanamineamp9542npmethylpalladiumiidichloromethanehemisolvate
AT emmanueliiwuoha chloridon2diphenylphosphanylbenzylidene22thienylethanamineamp9542npmethylpalladiumiidichloromethanehemisolvate
AT jamesdarkwa chloridon2diphenylphosphanylbenzylidene22thienylethanamineamp9542npmethylpalladiumiidichloromethanehemisolvate
AT rogeralalancette chloridon2diphenylphosphanylbenzylidene22thienylethanamineamp9542npmethylpalladiumiidichloromethanehemisolvate
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