Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ2N,P}methylpalladium(II) dichloromethane hemisolvate

Chlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-(2-thienyl)ethanamine-κ2N,P}methylpalladium(II) dichloromethane hemisolvate

In the title compound, [Pd(CH3)Cl(C25H22NPS)]·0.5C2H2Cl2, the PdII atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thiophene ring is equally disorde...

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Bibliographic Details
Main Authors: Martin O. Onani, William M. Motswainyana, Emmanuel I. Iwuoha, James Darkwa, Roger A. Lalancette
Format: Article
Language:English
Published: International Union of Crystallography 2010-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810017824
Description
Summary:In the title compound, [Pd(CH3)Cl(C25H22NPS)]·0.5C2H2Cl2, the PdII atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thiophene ring is equally disordered over two orientations and the dichloromethane solvent molecule is disordered about an inversion centre.
ISSN:1600-5368

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