| Summary: | The main molecule of the title compound, C45H30N6·CH3OH, has a non-planar core: the dihedral angles between the benzimidazole rings and the central benzene ring are 20.19 (10), 34.57 (8), and 44.59 (8)°, while the dihedral angles between the peripheral phenyl rings and the attached benzimidazole rings are 84.57 (7), 62.71 (6) and 51.73 (6)°. The tri-substituted benzene molecule is connected to the methanol solvent molecule through an O—H...N hydrogen bond, forming a 1:1 solvate. In the crystal structure, no significant π–π interactions are present, and the molecules are associated through weak C—H...N and C—H...O(methanol) contacts.
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