Nickel(II) cyclohexylethyl-dithiocarbamate P-donor ligands in the coordination sphere
A series of new Ni(II) dithiocarbamate compounds of the composition [NiX(cetdtc)(PR3)](X = Cl, Br, I, NCS; cetdtc = cyclohexylethyldithiocarbamate; R = phenyl, n-butyl) has been synthesized. All the isolated complexes have been characterized by elemental analysis, IR and UV/VIS spectroscopy, 31P{1H}...
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Serbian Chemical Society
2004-01-01
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| Series: | Journal of the Serbian Chemical Society |
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| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2004/0352-51390412053H.pdf |
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doaj-3bc6b3cd27f0443e9bb77245afaeb50e2020-12-24T12:20:29ZengSerbian Chemical Society Journal of the Serbian Chemical Society0352-51391820-74212004-01-0169121053106110.2298/JSC0412053H0352-51390412053HNickel(II) cyclohexylethyl-dithiocarbamate P-donor ligands in the coordination sphereHusárek Josef0Pstorek Richard1Malon Michal2Šindalar Zedenek3Pavlíček Marek4Department of Inorganic Chemistry, Palacký University, Olomouc, Czech RepublicDepartment of Inorganic Chemistry, Palacký University, Olomouc, Czech RepublicDepartment of Inorganic Chemistry, Palacký University, Olomouc, Czech RepublicDepartment of Inorganic Chemistry, Palacký University, Olomouc, Czech RepublicDepartment of Inorganic Chemistry, Palacký University, Olomouc, Czech RepublicA series of new Ni(II) dithiocarbamate compounds of the composition [NiX(cetdtc)(PR3)](X = Cl, Br, I, NCS; cetdtc = cyclohexylethyldithiocarbamate; R = phenyl, n-butyl) has been synthesized. All the isolated complexes have been characterized by elemental analysis, IR and UV/VIS spectroscopy, 31P{1H}-NMR spectroscopy, thermal analysis magnetochemical and conductivity measurements. On the basis of the results of the physico-chemical study, all complexes are diamagnetic, non-electrolytes with a square-planar NiS2PX chromophore.http://www.doiserbia.nb.rs/img/doi/0352-5139/2004/0352-51390412053H.pdfnickel(ii) cyclohexylethyldithiocarbamate complexesmonodantate p-donor ligandssynthesis31pš1hć-nmr spectroscopy |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Husárek Josef Pstorek Richard Malon Michal Šindalar Zedenek Pavlíček Marek |
| spellingShingle |
Husárek Josef Pstorek Richard Malon Michal Šindalar Zedenek Pavlíček Marek Nickel(II) cyclohexylethyl-dithiocarbamate P-donor ligands in the coordination sphere Journal of the Serbian Chemical Society nickel(ii) cyclohexylethyldithiocarbamate complexes monodantate p-donor ligands synthesis 31pš1hć-nmr spectroscopy |
| author_facet |
Husárek Josef Pstorek Richard Malon Michal Šindalar Zedenek Pavlíček Marek |
| author_sort |
Husárek Josef |
| title |
Nickel(II) cyclohexylethyl-dithiocarbamate P-donor ligands in the coordination sphere |
| title_short |
Nickel(II) cyclohexylethyl-dithiocarbamate P-donor ligands in the coordination sphere |
| title_full |
Nickel(II) cyclohexylethyl-dithiocarbamate P-donor ligands in the coordination sphere |
| title_fullStr |
Nickel(II) cyclohexylethyl-dithiocarbamate P-donor ligands in the coordination sphere |
| title_full_unstemmed |
Nickel(II) cyclohexylethyl-dithiocarbamate P-donor ligands in the coordination sphere |
| title_sort |
nickel(ii) cyclohexylethyl-dithiocarbamate p-donor ligands in the coordination sphere |
| publisher |
Serbian Chemical Society |
| series |
Journal of the Serbian Chemical Society |
| issn |
0352-5139 1820-7421 |
| publishDate |
2004-01-01 |
| description |
A series of new Ni(II) dithiocarbamate compounds of the composition [NiX(cetdtc)(PR3)](X = Cl, Br, I, NCS; cetdtc = cyclohexylethyldithiocarbamate; R = phenyl, n-butyl) has been synthesized. All the isolated complexes have been characterized by elemental analysis, IR and UV/VIS spectroscopy, 31P{1H}-NMR spectroscopy, thermal analysis magnetochemical and conductivity measurements. On the basis of the results of the physico-chemical study, all complexes are diamagnetic, non-electrolytes with a square-planar NiS2PX chromophore. |
| topic |
nickel(ii) cyclohexylethyldithiocarbamate complexes monodantate p-donor ligands synthesis 31pš1hć-nmr spectroscopy |
| url |
http://www.doiserbia.nb.rs/img/doi/0352-5139/2004/0352-51390412053H.pdf |
| work_keys_str_mv |
AT husarekjosef nickeliicyclohexylethyldithiocarbamatepdonorligandsinthecoordinationsphere AT pstorekrichard nickeliicyclohexylethyldithiocarbamatepdonorligandsinthecoordinationsphere AT malonmichal nickeliicyclohexylethyldithiocarbamatepdonorligandsinthecoordinationsphere AT sindalarzedenek nickeliicyclohexylethyldithiocarbamatepdonorligandsinthecoordinationsphere AT pavlicekmarek nickeliicyclohexylethyldithiocarbamatepdonorligandsinthecoordinationsphere |
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