Chloro({2-[mesityl(quinolin-8-yl-κN)boryl]-3,5-dimethyl-phenyl}methyl-κC)palladium(II) as a Catalyst for Heck Reactions

Chloro({2-[mesityl(quinolin-8-yl-κN)boryl]-3,5-dimethyl-phenyl}methyl-κC)palladium(II) as a Catalyst for Heck Reactions

We recently reported an air and moisture stable 16-electron borapalladacycle formed upon combination of 8-quinolyldimesitylborane with bis(benzonitrile)dichloropalladium(II). The complex features a tucked mesityl group formed upon metalation of an ortho-methyl group on a mesityl; however it is unusu...

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Bibliographic Details
Main Authors: Sem Raj Tamang, James D. Hoefelmeyer
Format: Article
Language:English
Published: MDPI AG 2015-07-01
Series:Molecules
Subjects:
Heck reaction
catalysis
organometallic
palladium
frustrated Lewis pair
non-classical ligand
Online Access:http://www.mdpi.com/1420-3049/20/7/12979

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