Comparation of fundamental analytical methods for quantitative determination of copper(II)ion

• Main Author: Ačanski Marijana M.
• Format: Article
• Language: English
• Published: Association of Chemical Engineers of Serbia 2008-01-01
• Series: Hemijska Industrija
• Subjects: copper(II) ion; quantitative chemistry analysis (gravimetric and titrimetric)
• Online Access: http://www.doiserbia.nb.rs/img/doi/0367-598X/2008/0367-598X0802085A.pdf

Copper is a ductile metal with excellent electrical conductivity, and finds extensive use as an electrical conductor, heat conductor, as a building material, and as a component of various alloys. In this work accuracy of methods for quantitative determination (gravimetric and titrimetric methods of analysis) of copper(II) ion was studied. Gravimetric methods do not require a calibration or standardization step (as all other analytical procedures except coulometry do) because the results are calculated directly from the experimental data and molar masses. Thus, when only one or two samples are to be analyzed, a gravimetric procedure may be the method of choice because it involves less time and effort than a procedure that requires preparation of standards and calibration. In this work in gravimetric analysis the concentration of copper(II) ion is established through the measurement of a mass of CuSCN and CuO. Titrimetric methods is a process in which a standard reagent is added to a solution of an analyze until the reaction between the analyze and reagent is judged to be complete. In this work in titrimetric analysis the concentration of copper(II) ion is established through the measurement of a volume of different standard reagents: Km, Na2S2O3 and AgNO3. Results were discussed individually and mutually with the aspect of exactility, reproductivity and rapidity. Relative error was calculated for all methods.