Reciclagem do crômio de resíduos químicos provenientes da determinação de carbono oxidável em fertilizantes orgânicos

• Main Authors: Jeane M. C Machado, Lenita M. C. P. E Oliveira, Marcos Y Kamogawa
• Format: Article
• Language: English
• Published: Sociedade Brasileira de Química 2011-01-01
• Series: Química Nova
• Subjects: dichromate ion; recycling; organic carbon analysis
• Online Access: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422011000100024&lng=en&tlng=en

This work proposes a separation, recovery and reuse procedure of chemical residues with chromium. This residue was generated by the determination of oxidizable carbon in organic fertilizers samples. The Cr(VI) of the residue was reduced with ethanol and precipitated with NaOH. The Cr(OH)3 precipitate was separated and oxidized to dichromate ions with hydrogen peroxide. This solution was used another time in organic carbon determination. The uses of recycled dichromate solution were appropriated in four successive recycling. The accuracy was proven using potassium hydrogen phthalate and ten organic fertilizer samples. The organic carbon results, determined with recycled solutions, were similar the conventional solution.