Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDA
The first example of silver-mediated phosphine-promoted methoxylation of aryl C(<i>sp</i><sup>2</sup>)⁻H bonds with the commercially available reagent for the preparation of alkyl aryl ethers has been developed. This protocol is characterized by mild reaction condit...
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2019-02-01
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Online Access: | https://www.mdpi.com/2073-4344/9/2/171 |
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doaj-3af30d3611514169bf991eef60519f192020-11-25T02:10:51ZengMDPI AGCatalysts2073-43442019-02-019217110.3390/catal9020171catal9020171Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDAGuofu Zhang0Jianfei Zhu1Lidi Xuan2Chengrong Ding3College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaThe first example of silver-mediated phosphine-promoted methoxylation of aryl C(<i>sp</i><sup>2</sup>)⁻H bonds with the commercially available reagent for the preparation of alkyl aryl ethers has been developed. This protocol is characterized by mild reaction conditions, broad substrate scope, and high regioselectivity.https://www.mdpi.com/2073-4344/9/2/171Silver-mediatedphosphine-promotedC–H functionalizationDMEDApharmaceutical development |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Guofu Zhang Jianfei Zhu Lidi Xuan Chengrong Ding |
spellingShingle |
Guofu Zhang Jianfei Zhu Lidi Xuan Chengrong Ding Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDA Catalysts Silver-mediated phosphine-promoted C–H functionalization DMEDA pharmaceutical development |
author_facet |
Guofu Zhang Jianfei Zhu Lidi Xuan Chengrong Ding |
author_sort |
Guofu Zhang |
title |
Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDA |
title_short |
Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDA |
title_full |
Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDA |
title_fullStr |
Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDA |
title_full_unstemmed |
Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDA |
title_sort |
silver-mediated methoxylation of aryl c(<i>sp</i><sup>2</sup>)–h bonds directing by dmeda |
publisher |
MDPI AG |
series |
Catalysts |
issn |
2073-4344 |
publishDate |
2019-02-01 |
description |
The first example of silver-mediated phosphine-promoted methoxylation of aryl C(<i>sp</i><sup>2</sup>)⁻H bonds with the commercially available reagent for the preparation of alkyl aryl ethers has been developed. This protocol is characterized by mild reaction conditions, broad substrate scope, and high regioselectivity. |
topic |
Silver-mediated phosphine-promoted C–H functionalization DMEDA pharmaceutical development |
url |
https://www.mdpi.com/2073-4344/9/2/171 |
work_keys_str_mv |
AT guofuzhang silvermediatedmethoxylationofarylcispisup2suphbondsdirectingbydmeda AT jianfeizhu silvermediatedmethoxylationofarylcispisup2suphbondsdirectingbydmeda AT lidixuan silvermediatedmethoxylationofarylcispisup2suphbondsdirectingbydmeda AT chengrongding silvermediatedmethoxylationofarylcispisup2suphbondsdirectingbydmeda |
_version_ |
1724916958698143744 |