Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDA

The first example of silver-mediated phosphine-promoted methoxylation of aryl C(<i>sp</i><sup>2</sup>)&#8315;H bonds with the commercially available reagent for the preparation of alkyl aryl ethers has been developed. This protocol is characterized by mild reaction condit...

Full description

Bibliographic Details
Main Authors: Guofu Zhang, Jianfei Zhu, Lidi Xuan, Chengrong Ding
Format: Article
Language:English
Published: MDPI AG 2019-02-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/9/2/171
id doaj-3af30d3611514169bf991eef60519f19
record_format Article
spelling doaj-3af30d3611514169bf991eef60519f192020-11-25T02:10:51ZengMDPI AGCatalysts2073-43442019-02-019217110.3390/catal9020171catal9020171Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDAGuofu Zhang0Jianfei Zhu1Lidi Xuan2Chengrong Ding3College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaThe first example of silver-mediated phosphine-promoted methoxylation of aryl C(<i>sp</i><sup>2</sup>)&#8315;H bonds with the commercially available reagent for the preparation of alkyl aryl ethers has been developed. This protocol is characterized by mild reaction conditions, broad substrate scope, and high regioselectivity.https://www.mdpi.com/2073-4344/9/2/171Silver-mediatedphosphine-promotedC–H functionalizationDMEDApharmaceutical development
collection DOAJ
language English
format Article
sources DOAJ
author Guofu Zhang
Jianfei Zhu
Lidi Xuan
Chengrong Ding
spellingShingle Guofu Zhang
Jianfei Zhu
Lidi Xuan
Chengrong Ding
Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDA
Catalysts
Silver-mediated
phosphine-promoted
C–H functionalization
DMEDA
pharmaceutical development
author_facet Guofu Zhang
Jianfei Zhu
Lidi Xuan
Chengrong Ding
author_sort Guofu Zhang
title Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDA
title_short Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDA
title_full Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDA
title_fullStr Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDA
title_full_unstemmed Silver-Mediated Methoxylation of Aryl C(<i>sp</i><sup>2</sup>)–H Bonds Directing by DMEDA
title_sort silver-mediated methoxylation of aryl c(<i>sp</i><sup>2</sup>)–h bonds directing by dmeda
publisher MDPI AG
series Catalysts
issn 2073-4344
publishDate 2019-02-01
description The first example of silver-mediated phosphine-promoted methoxylation of aryl C(<i>sp</i><sup>2</sup>)&#8315;H bonds with the commercially available reagent for the preparation of alkyl aryl ethers has been developed. This protocol is characterized by mild reaction conditions, broad substrate scope, and high regioselectivity.
topic Silver-mediated
phosphine-promoted
C–H functionalization
DMEDA
pharmaceutical development
url https://www.mdpi.com/2073-4344/9/2/171
work_keys_str_mv AT guofuzhang silvermediatedmethoxylationofarylcispisup2suphbondsdirectingbydmeda
AT jianfeizhu silvermediatedmethoxylationofarylcispisup2suphbondsdirectingbydmeda
AT lidixuan silvermediatedmethoxylationofarylcispisup2suphbondsdirectingbydmeda
AT chengrongding silvermediatedmethoxylationofarylcispisup2suphbondsdirectingbydmeda
_version_ 1724916958698143744