Development of a Methodology for Determining Major Ions in Samples of Atmospheric Particulate Matter by Ion Chromatography

• Main Authors: José Domingos Santos da Silva, Alexandre Varão Moura, Thamilin Costa Nakamura, Enoc Lima do Rego, Priscila Gubert, Stelyus Lazaro Mkoma, Gisele Olimpio da Rocha
• Format: Article
• Language: English
• Published: Universidade Federal de Mato Grosso do Sul 2020-12-01
• Series: Orbital: The Electronic Journal of Chemistry
• Subjects: ion chromatography; environmental samples; major water-soluble ions; particulate matter
• Online Access: http://orbital.ufms.br/index.php/Chemistry/article/view/1494

<p class="Normal1">Countless deleterious effects on human health and the environment are promoted by the action of air pollutants. Thus, it is necessary the development of analytical methods to identify and quantify efficiently ions present in atmospheric particulate matter. This study proposes a new analytical methodology for simultaneous quantification of 12 organic ions (Lactate, Acetate, Propionate, Formate, Butyrate, Methanesulfonate, Pyruvate, Monochloroacetate, Trifluoroacetate, Succinate, Oxalate and Citrate), 12 inorganic anions (fluoride, bromate, chloride, nitrite, bromide, nitrate, sulfite, sulfate, tungstade, molybdate, phosphate and chromate) and 7 cations (lithium, sodium, ammonium, potassium, magnesium, calcium and strontium) using ion chromatography coupled to conductivity detection. The optimization of the proposed method was performed univariate and validation was done according to IUPAC recommendations; LOD and LOQ varied between 12 to 114 pg m^-3 and 35 to 342 pg m^-3 respectively, showing recovery values between 89% to 109% and R² between 0.9979 and 0.9999 for the 31 main ions studied. Ions were successfully determined in environmental samples of particulate material in the 10 µm and 2.5 µm fractions. This method was considered a comprehensive, accurate, fast and robust procedure for the study of ions in samples of atmospheric particulate matter.</p><p class="Normal1"> </p><p class="Normal1">DOI: <a href="http://dx.doi.org/10.17807/orbital.v12i4.1494">http://dx.doi.org/10.17807/orbital.v12i4.1494</a></p><br />