Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate]

Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate]

The asymmetric unit of the title compound, {[Zn(C16H16O4Si)(C12H10N4)]·H2O}n, consists of one ZnII ion, two half 3,3′-(dimethylsilanediyl)dibenzoate ligands and two half 1,1′-(1,4-phenylene)di-1H-imidazole ligands. The ZnII ion is four-coordinated by two O at...

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Main Authors: Guohui Huang, Yiling Bei
Format: Article
Language:English
Published: International Union of Crystallography 2012-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812019642
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spelling doaj-3a6d1a2cd71c45efb3609a2154051c2c2020-11-25T01:22:58ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m865m86610.1107/S1600536812019642Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate]Guohui HuangYiling BeiThe asymmetric unit of the title compound, {[Zn(C16H16O4Si)(C12H10N4)]·H2O}n, consists of one ZnII ion, two half 3,3′-(dimethylsilanediyl)dibenzoate ligands and two half 1,1′-(1,4-phenylene)di-1H-imidazole ligands. The ZnII ion is four-coordinated by two O atoms from two carboxlate ligands, two N atoms from two imidazole ligands. Two ZnII ions are bridged by two carboxylate groups in chelating mode, generating a binuclear secondary building unit (SBU), which is further coordinated by two N atoms from two imidazole ligands in monodentate mode. Thus, the binuclear SBUs are further bridged by imidazole ligands in two different directions, giving rise to a chain. The water solvent molecules are hydrogen bonded within the chain along the c axis.http://scripts.iucr.org/cgi-bin/paper?S1600536812019642
collection DOAJ
language English
format Article
sources DOAJ
author Guohui Huang
Yiling Bei
spellingShingle Guohui Huang
Yiling Bei
Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate]
Acta Crystallographica Section E
author_facet Guohui Huang
Yiling Bei
author_sort Guohui Huang
title Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate]
title_short Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate]
title_full Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate]
title_fullStr Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate]
title_full_unstemmed Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate]
title_sort poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1h-imidazole]zinc] monohydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-07-01
description The asymmetric unit of the title compound, {[Zn(C16H16O4Si)(C12H10N4)]·H2O}n, consists of one ZnII ion, two half 3,3′-(dimethylsilanediyl)dibenzoate ligands and two half 1,1′-(1,4-phenylene)di-1H-imidazole ligands. The ZnII ion is four-coordinated by two O atoms from two carboxlate ligands, two N atoms from two imidazole ligands. Two ZnII ions are bridged by two carboxylate groups in chelating mode, generating a binuclear secondary building unit (SBU), which is further coordinated by two N atoms from two imidazole ligands in monodentate mode. Thus, the binuclear SBUs are further bridged by imidazole ligands in two different directions, giving rise to a chain. The water solvent molecules are hydrogen bonded within the chain along the c axis.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812019642
work_keys_str_mv AT guohuihuang polyamp95633amp8242dimethylsilanediyldibenzoatoamp95611amp824214phenylenedi1himidazolezincmonohydrate
AT yilingbei polyamp95633amp8242dimethylsilanediyldibenzoatoamp95611amp824214phenylenedi1himidazolezincmonohydrate
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