Eco-benign biodiesel production from waste cooking oil using eggshell derived MM-CaO catalyst and condition optimization using RSM approach

Eco-benign biodiesel production from waste cooking oil using eggshell derived MM-CaO catalyst and condition optimization using RSM approach

Fatty acid methyl ester (FAME) was produced from waste cooking oil (WCO) utilizing eggshells derived solid base catalyst. Eggshells derived multi modal CaO (MM-CaO) also provides a cost-effective way for the preparation of green fuel. The nano-scaled MM-CaO was prepared using ball milling followed b...

Full description

Bibliographic Details
Main Authors: F. Nadeem, I.A. Bhatti, A. Ashar, M. Yousaf, M. Iqbal, M. Mohsin, J. Nisar, N. Tamam, N. Alwadai
Format: Article
Language:English
Published: Elsevier 2021-08-01
Series:Arabian Journal of Chemistry
Subjects:
Heterogeneous catalyst
Waste cooking oil
Eggshells
Biodiesel properties
Online Access:http://www.sciencedirect.com/science/article/pii/S1878535221002781
id doaj-39b8e98da6794670818eb5555bbf2782
record_format Article
spelling doaj-39b8e98da6794670818eb5555bbf27822021-07-23T04:48:14ZengElsevierArabian Journal of Chemistry1878-53522021-08-01148103263Eco-benign biodiesel production from waste cooking oil using eggshell derived MM-CaO catalyst and condition optimization using RSM approachF. Nadeem0I.A. Bhatti1A. Ashar2M. Yousaf3M. Iqbal4M. Mohsin5J. Nisar6N. Tamam7N. Alwadai8Department of Chemistry, University of Agriculture, Faisalabad, PakistanDepartment of Chemistry, University of Agriculture, Faisalabad, PakistanDepartment of Chemistry, University of Agriculture, Faisalabad, Pakistan; Department of Chemistry, Govt. College Women University, Faisalabad, Pakistan; Corresponding author.Department of Chemistry, University of Agriculture, Faisalabad, PakistanDepartment of Chemistry, The University of Lahore, Lahore, Pakistan; Corresponding author.Department of Chemistry, University of Agriculture, Faisalabad, PakistanNational Centre of Excellence in Physical Chemistry, University of Peshawar, Peshawar 25120, PakistanDepartment of Physics, College of Sciences, Princess Nourah bint Abdulrahman University (PNU), Riyadh 11671, Saudi Arabia; Corresponding author.Department of Physics, College of Sciences, Princess Nourah bint Abdulrahman University (PNU), Riyadh 11671, Saudi ArabiaFatty acid methyl ester (FAME) was produced from waste cooking oil (WCO) utilizing eggshells derived solid base catalyst. Eggshells derived multi modal CaO (MM-CaO) also provides a cost-effective way for the preparation of green fuel. The nano-scaled MM-CaO was prepared using ball milling followed by calcination at 800 °C for 2 h form eggshells powder. The characterization of calcined powder was executed by XRD, EDX, SEM and FTIR techniques. Diffractogram of MM-CaO showed cubic crystal structure and presence of calcium, carbon and oxygen was confirmed by EDX. The morphology of MM-CaO was revealed by SEM having bandgap energy (3.02 eV) which declared MM-CaO as photoactive in solar range. Catalytic transesterification process furnished 75.2% yield, whereas in photocatalytic process, 86.8% yield was obtained at optimum conditions (temperature 50 °C, reaction time 180 min and 1.5 g catalyst dose). The FAME formation was monitored by GC and FTIR analysis. Physiochemical properties of produced biodiesel were also determined and equated with standards. Results depicted that MM-CaO is highly efficient for conversion of WCO to biodiesel.http://www.sciencedirect.com/science/article/pii/S1878535221002781Heterogeneous catalystWaste cooking oilEggshellsBiodiesel properties
collection DOAJ
language English
format Article
sources DOAJ
author F. Nadeem
I.A. Bhatti
A. Ashar
M. Yousaf
M. Iqbal
M. Mohsin
J. Nisar
N. Tamam
N. Alwadai
spellingShingle F. Nadeem
I.A. Bhatti
A. Ashar
M. Yousaf
M. Iqbal
M. Mohsin
J. Nisar
N. Tamam
N. Alwadai
Eco-benign biodiesel production from waste cooking oil using eggshell derived MM-CaO catalyst and condition optimization using RSM approach
Arabian Journal of Chemistry
Heterogeneous catalyst
Waste cooking oil
Eggshells
Biodiesel properties
author_facet F. Nadeem
I.A. Bhatti
A. Ashar
M. Yousaf
M. Iqbal
M. Mohsin
J. Nisar
N. Tamam
N. Alwadai
author_sort F. Nadeem
title Eco-benign biodiesel production from waste cooking oil using eggshell derived MM-CaO catalyst and condition optimization using RSM approach
title_short Eco-benign biodiesel production from waste cooking oil using eggshell derived MM-CaO catalyst and condition optimization using RSM approach
title_full Eco-benign biodiesel production from waste cooking oil using eggshell derived MM-CaO catalyst and condition optimization using RSM approach
title_fullStr Eco-benign biodiesel production from waste cooking oil using eggshell derived MM-CaO catalyst and condition optimization using RSM approach
title_full_unstemmed Eco-benign biodiesel production from waste cooking oil using eggshell derived MM-CaO catalyst and condition optimization using RSM approach
title_sort eco-benign biodiesel production from waste cooking oil using eggshell derived mm-cao catalyst and condition optimization using rsm approach
publisher Elsevier
series Arabian Journal of Chemistry
issn 1878-5352
publishDate 2021-08-01
description Fatty acid methyl ester (FAME) was produced from waste cooking oil (WCO) utilizing eggshells derived solid base catalyst. Eggshells derived multi modal CaO (MM-CaO) also provides a cost-effective way for the preparation of green fuel. The nano-scaled MM-CaO was prepared using ball milling followed by calcination at 800 °C for 2 h form eggshells powder. The characterization of calcined powder was executed by XRD, EDX, SEM and FTIR techniques. Diffractogram of MM-CaO showed cubic crystal structure and presence of calcium, carbon and oxygen was confirmed by EDX. The morphology of MM-CaO was revealed by SEM having bandgap energy (3.02 eV) which declared MM-CaO as photoactive in solar range. Catalytic transesterification process furnished 75.2% yield, whereas in photocatalytic process, 86.8% yield was obtained at optimum conditions (temperature 50 °C, reaction time 180 min and 1.5 g catalyst dose). The FAME formation was monitored by GC and FTIR analysis. Physiochemical properties of produced biodiesel were also determined and equated with standards. Results depicted that MM-CaO is highly efficient for conversion of WCO to biodiesel.
topic Heterogeneous catalyst
Waste cooking oil
Eggshells
Biodiesel properties
url http://www.sciencedirect.com/science/article/pii/S1878535221002781
work_keys_str_mv AT fnadeem ecobenignbiodieselproductionfromwastecookingoilusingeggshellderivedmmcaocatalystandconditionoptimizationusingrsmapproach
AT iabhatti ecobenignbiodieselproductionfromwastecookingoilusingeggshellderivedmmcaocatalystandconditionoptimizationusingrsmapproach
AT aashar ecobenignbiodieselproductionfromwastecookingoilusingeggshellderivedmmcaocatalystandconditionoptimizationusingrsmapproach
AT myousaf ecobenignbiodieselproductionfromwastecookingoilusingeggshellderivedmmcaocatalystandconditionoptimizationusingrsmapproach
AT miqbal ecobenignbiodieselproductionfromwastecookingoilusingeggshellderivedmmcaocatalystandconditionoptimizationusingrsmapproach
AT mmohsin ecobenignbiodieselproductionfromwastecookingoilusingeggshellderivedmmcaocatalystandconditionoptimizationusingrsmapproach
AT jnisar ecobenignbiodieselproductionfromwastecookingoilusingeggshellderivedmmcaocatalystandconditionoptimizationusingrsmapproach
AT ntamam ecobenignbiodieselproductionfromwastecookingoilusingeggshellderivedmmcaocatalystandconditionoptimizationusingrsmapproach
AT nalwadai ecobenignbiodieselproductionfromwastecookingoilusingeggshellderivedmmcaocatalystandconditionoptimizationusingrsmapproach
_version_ 1721290607536635904

Similar Items