Kinetic, mechanistic, and spectroscopic studies of permanganate oxidation of azinylformamidines in acidic medium, with autocatalytic behavior of manganese(II)
The kinetics of permanganate oxidation of two substituted azinylformamidines (Azn-Fs), namely N,N-dimethyl-N′-(pyridin-2-yl)formamidine (Py) and N,N-dimethyl-N′-(pyrimidin-2-yl)formamidine (Pym), in sulfuric acid were investigated using conventional spectrophotometry. Kinetic evidence for the format...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2016-09-01
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| Series: | Journal of Saudi Chemical Society |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S131961031400180X |