Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione

12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione (quinone 2) served as the dienophile in numerous intermolecular Diels-Alder reactions. These cycloadditions were conducted either thermally (including microwave heating) or with Lewis acid activation. While most dienes reacted...

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Main Authors: Shougang Hu, Yangyang Wang, Yang Li, Ge Zou, Xinrong Tian, Yong Zhang, George Majetich, Eric Huddleston
Format: Article
Language:English
Published: MDPI AG 2013-06-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/18/6/6969
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spelling doaj-392b99ee68f94bb88b5c8cf0549016722020-11-24T20:44:56ZengMDPI AGMolecules1420-30492013-06-011866969698910.3390/molecules18066969Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dioneShougang HuYangyang WangYang LiGe ZouXinrong TianYong ZhangGeorge MajetichEric Huddleston12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione (quinone 2) served as the dienophile in numerous intermolecular Diels-Alder reactions. These cycloadditions were conducted either thermally (including microwave heating) or with Lewis acid activation. While most dienes reacted with quinone 2 in good chemical yield, others were incompatible under the experimental conditions used.http://www.mdpi.com/1420-3049/18/6/6969Diels-Alder reactioncascade processone-pot reactionLewis acid catalysis
collection DOAJ
language English
format Article
sources DOAJ
author Shougang Hu
Yangyang Wang
Yang Li
Ge Zou
Xinrong Tian
Yong Zhang
George Majetich
Eric Huddleston
spellingShingle Shougang Hu
Yangyang Wang
Yang Li
Ge Zou
Xinrong Tian
Yong Zhang
George Majetich
Eric Huddleston
Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione
Molecules
Diels-Alder reaction
cascade process
one-pot reaction
Lewis acid catalysis
author_facet Shougang Hu
Yangyang Wang
Yang Li
Ge Zou
Xinrong Tian
Yong Zhang
George Majetich
Eric Huddleston
author_sort Shougang Hu
title Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione
title_short Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione
title_full Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione
title_fullStr Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione
title_full_unstemmed Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione
title_sort diels-alder reactions of 12-hydroxy-9(10®20)-5ah-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione
publisher MDPI AG
series Molecules
issn 1420-3049
publishDate 2013-06-01
description 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione (quinone 2) served as the dienophile in numerous intermolecular Diels-Alder reactions. These cycloadditions were conducted either thermally (including microwave heating) or with Lewis acid activation. While most dienes reacted with quinone 2 in good chemical yield, others were incompatible under the experimental conditions used.
topic Diels-Alder reaction
cascade process
one-pot reaction
Lewis acid catalysis
url http://www.mdpi.com/1420-3049/18/6/6969
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