Bis(but-2-enoato-κO)triphenylbismuth(V)
In the title molecule, [Bi(C6H5)3(C4H5O2)2], the BiV atom is in a distorted trigonal–bipyramidal environment with carboxylate O atoms in axial positions and phenyl C atoms in the equatorial plane. The Bi—O bond lengths are 2.283 (3) and 2.309 (2) &am...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-06-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813013317 |
| id |
doaj-38d090db7a41438caf33f56b688a282b |
|---|---|
| record_format |
Article |
| spelling |
doaj-38d090db7a41438caf33f56b688a282b2020-11-24T21:55:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-06-01696m333m33310.1107/S1600536813013317Bis(but-2-enoato-κO)triphenylbismuth(V)Pavel V. AndreevNikolay V. SomovOlga S. KalistratovaAlexey V. GushchinEvgeny V. ChuprunovIn the title molecule, [Bi(C6H5)3(C4H5O2)2], the BiV atom is in a distorted trigonal–bipyramidal environment with carboxylate O atoms in axial positions and phenyl C atoms in the equatorial plane. The Bi—O bond lengths are 2.283 (3) and 2.309 (2) Å, but as a result of additional long Bi...O interactions [2.787 (3) and 2.734 (3) Å], one of the C—Bi—C angles is 148.62 (13)°. In the crystal, weak C—H...O hydrogen bonds connect pairs of molecules into inversion dimers. These dimers are further connected by weak C—H...π interactions into chains along [100] .http://scripts.iucr.org/cgi-bin/paper?S1600536813013317 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Pavel V. Andreev Nikolay V. Somov Olga S. Kalistratova Alexey V. Gushchin Evgeny V. Chuprunov |
| spellingShingle |
Pavel V. Andreev Nikolay V. Somov Olga S. Kalistratova Alexey V. Gushchin Evgeny V. Chuprunov Bis(but-2-enoato-κO)triphenylbismuth(V) Acta Crystallographica Section E |
| author_facet |
Pavel V. Andreev Nikolay V. Somov Olga S. Kalistratova Alexey V. Gushchin Evgeny V. Chuprunov |
| author_sort |
Pavel V. Andreev |
| title |
Bis(but-2-enoato-κO)triphenylbismuth(V) |
| title_short |
Bis(but-2-enoato-κO)triphenylbismuth(V) |
| title_full |
Bis(but-2-enoato-κO)triphenylbismuth(V) |
| title_fullStr |
Bis(but-2-enoato-κO)triphenylbismuth(V) |
| title_full_unstemmed |
Bis(but-2-enoato-κO)triphenylbismuth(V) |
| title_sort |
bis(but-2-enoato-κo)triphenylbismuth(v) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2013-06-01 |
| description |
In the title molecule, [Bi(C6H5)3(C4H5O2)2], the BiV atom is in a distorted trigonal–bipyramidal environment with carboxylate O atoms in axial positions and phenyl C atoms in the equatorial plane. The Bi—O bond lengths are 2.283 (3) and 2.309 (2) Å, but as a result of additional long Bi...O interactions [2.787 (3) and 2.734 (3) Å], one of the C—Bi—C angles is 148.62 (13)°. In the crystal, weak C—H...O hydrogen bonds connect pairs of molecules into inversion dimers. These dimers are further connected by weak C—H...π interactions into chains along [100] . |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536813013317 |
| work_keys_str_mv |
AT pavelvandreev bisbut2enoato954otriphenylbismuthv AT nikolayvsomov bisbut2enoato954otriphenylbismuthv AT olgaskalistratova bisbut2enoato954otriphenylbismuthv AT alexeyvgushchin bisbut2enoato954otriphenylbismuthv AT evgenyvchuprunov bisbut2enoato954otriphenylbismuthv |
| _version_ |
1725860862966628352 |