The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents

The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents

Wittig-Horner reagents 1a,b react with 1,2,3-indantrione (2) to give the dimeric adducts 3a and 3b, respectively. Moreover, 2 reacts with tert-butyl diethylphosphonoacetate (1c) yielding the ethylenic compound 4. On the other hand, 2 reacts with 1d to yield the phosphonate adduct 5. Mechanisms accou...

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Main Authors: L. S. Boulos, N. M. Abd El-Rahman
Format: Article
Language:English
Published: MDPI AG 2002-01-01
Series:Molecules
Subjects:
1
2
3-Indantrione
Wittig-Horner reagents
phosphonate
spiroadduct
Online Access:http://www.mdpi.com/1420-3049/7/1/81/
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spelling doaj-38cc07b3b037487386fc64688e7d984e2020-11-24T23:56:48ZengMDPI AGMolecules1420-30492002-01-0171818810.3390/70100081The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner ReagentsL. S. BoulosN. M. Abd El-RahmanWittig-Horner reagents 1a,b react with 1,2,3-indantrione (2) to give the dimeric adducts 3a and 3b, respectively. Moreover, 2 reacts with tert-butyl diethylphosphonoacetate (1c) yielding the ethylenic compound 4. On the other hand, 2 reacts with 1d to yield the phosphonate adduct 5. Mechanisms accounting for the formation of the new products are discussed and the probable structures of the products are presented based on compatible analytical and spectral data.http://www.mdpi.com/1420-3049/7/1/81/123-IndantrioneWittig-Horner reagentsphosphonatespiroadduct
collection DOAJ
language English
format Article
sources DOAJ
author L. S. Boulos
N. M. Abd El-Rahman
spellingShingle L. S. Boulos
N. M. Abd El-Rahman
The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents
Molecules
1
2
3-Indantrione
Wittig-Horner reagents
phosphonate
spiroadduct
author_facet L. S. Boulos
N. M. Abd El-Rahman
author_sort L. S. Boulos
title The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents
title_short The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents
title_full The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents
title_fullStr The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents
title_full_unstemmed The Behaviour of 1,2,3-Indantrione Towards Wittig-Horner Reagents
title_sort behaviour of 1,2,3-indantrione towards wittig-horner reagents
publisher MDPI AG
series Molecules
issn 1420-3049
publishDate 2002-01-01
description Wittig-Horner reagents 1a,b react with 1,2,3-indantrione (2) to give the dimeric adducts 3a and 3b, respectively. Moreover, 2 reacts with tert-butyl diethylphosphonoacetate (1c) yielding the ethylenic compound 4. On the other hand, 2 reacts with 1d to yield the phosphonate adduct 5. Mechanisms accounting for the formation of the new products are discussed and the probable structures of the products are presented based on compatible analytical and spectral data.
topic 1
2
3-Indantrione
Wittig-Horner reagents
phosphonate
spiroadduct
url http://www.mdpi.com/1420-3049/7/1/81/
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