On-surface synthesis of planar dendrimers via divergent cross-coupling reaction

Although many strategies exist to synthesize dendrimers in solution, the synthesis of planar dendrimers on a surface has proven challenging. Here, the authors produce planar dendrimers through a divergent on-surface cross-coupling reaction between one aryl bromide and two isocyanides, which enables...

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Main Authors:	Deng-Yuan Li, Shi-Wen Li, Yu-Li Xie, Xin Hua, Yi-Tao Long, An Wang, Pei-Nian Liu
Format:	Article
Language:	English
Published:	Nature Publishing Group 2019-06-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-019-10407-6

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spelling	doaj-389a82cb094c4844a39dbdffe716d2482021-05-11T11:53:16ZengNature Publishing GroupNature Communications2041-17232019-06-011011910.1038/s41467-019-10407-6On-surface synthesis of planar dendrimers via divergent cross-coupling reactionDeng-Yuan Li0Shi-Wen Li1Yu-Li Xie2Xin Hua3Yi-Tao Long4An Wang5Pei-Nian Liu6Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, State Key Laboratory of Chemical Engineering, School of Chemistry and Molecular Engineering, East China University of Science & TechnologyKey Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, State Key Laboratory of Chemical Engineering, School of Chemistry and Molecular Engineering, East China University of Science & TechnologyKey Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, State Key Laboratory of Chemical Engineering, School of Chemistry and Molecular Engineering, East China University of Science & TechnologyKey Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, State Key Laboratory of Chemical Engineering, School of Chemistry and Molecular Engineering, East China University of Science & TechnologyKey Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, State Key Laboratory of Chemical Engineering, School of Chemistry and Molecular Engineering, East China University of Science & TechnologyKey Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, State Key Laboratory of Chemical Engineering, School of Chemistry and Molecular Engineering, East China University of Science & TechnologyKey Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, State Key Laboratory of Chemical Engineering, School of Chemistry and Molecular Engineering, East China University of Science & TechnologyAlthough many strategies exist to synthesize dendrimers in solution, the synthesis of planar dendrimers on a surface has proven challenging. Here, the authors produce planar dendrimers through a divergent on-surface cross-coupling reaction between one aryl bromide and two isocyanides, which enables the growth of branches from a single reactive site.https://doi.org/10.1038/s41467-019-10407-6
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Deng-Yuan Li Shi-Wen Li Yu-Li Xie Xin Hua Yi-Tao Long An Wang Pei-Nian Liu
spellingShingle	Deng-Yuan Li Shi-Wen Li Yu-Li Xie Xin Hua Yi-Tao Long An Wang Pei-Nian Liu On-surface synthesis of planar dendrimers via divergent cross-coupling reaction Nature Communications
author_facet	Deng-Yuan Li Shi-Wen Li Yu-Li Xie Xin Hua Yi-Tao Long An Wang Pei-Nian Liu
author_sort	Deng-Yuan Li
title	On-surface synthesis of planar dendrimers via divergent cross-coupling reaction
title_short	On-surface synthesis of planar dendrimers via divergent cross-coupling reaction
title_full	On-surface synthesis of planar dendrimers via divergent cross-coupling reaction
title_fullStr	On-surface synthesis of planar dendrimers via divergent cross-coupling reaction
title_full_unstemmed	On-surface synthesis of planar dendrimers via divergent cross-coupling reaction
title_sort	on-surface synthesis of planar dendrimers via divergent cross-coupling reaction
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2019-06-01
description	Although many strategies exist to synthesize dendrimers in solution, the synthesis of planar dendrimers on a surface has proven challenging. Here, the authors produce planar dendrimers through a divergent on-surface cross-coupling reaction between one aryl bromide and two isocyanides, which enables the growth of branches from a single reactive site.
url	https://doi.org/10.1038/s41467-019-10407-6
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On-surface synthesis of planar dendrimers via divergent cross-coupling reaction

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