On-surface synthesis of planar dendrimers via divergent cross-coupling reaction

Although many strategies exist to synthesize dendrimers in solution, the synthesis of planar dendrimers on a surface has proven challenging. Here, the authors produce planar dendrimers through a divergent on-surface cross-coupling reaction between one aryl bromide and two isocyanides, which enables...

Full description

Bibliographic Details
Main Authors: Deng-Yuan Li, Shi-Wen Li, Yu-Li Xie, Xin Hua, Yi-Tao Long, An Wang, Pei-Nian Liu
Format: Article
Language:English
Published: Nature Publishing Group 2019-06-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-019-10407-6
Description
Summary:Although many strategies exist to synthesize dendrimers in solution, the synthesis of planar dendrimers on a surface has proven challenging. Here, the authors produce planar dendrimers through a divergent on-surface cross-coupling reaction between one aryl bromide and two isocyanides, which enables the growth of branches from a single reactive site.
ISSN:2041-1723