Equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehyde

Equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehyde

Here we present equilibrium data for the cross-metathesis of methyl oleate (MO) with cinnamaldehyde (CA) obtained experimentally from liquid-phase catalytic tests conducted at 323 K. The reaction was carried out in batch reactors, using different reactant molar ratios and the 2nd generation Ru Hovey...

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Main Authors: Pablo D. Nieres, Andrés F. Trasarti, Carlos R. Apesteguía
Format: Article
Language:English
Published: Elsevier 2018-10-01
Series:Data in Brief
Online Access:http://www.sciencedirect.com/science/article/pii/S2352340918308436
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spelling doaj-385e993cd5b3409a8ec4fbd60438b5242020-11-24T21:47:22ZengElsevierData in Brief2352-34092018-10-0120190195Equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehydePablo D. Nieres0Andrés F. Trasarti1Carlos R. Apesteguía2Catalysis Science and Engineering Research Group (GICIC), INCAPE, UNL-CONICET, Predio CCT Conicet, Paraje El Pozo, 3000 Santa Fe, ArgentinaCatalysis Science and Engineering Research Group (GICIC), INCAPE, UNL-CONICET, Predio CCT Conicet, Paraje El Pozo, 3000 Santa Fe, ArgentinaCorresponding author.; Catalysis Science and Engineering Research Group (GICIC), INCAPE, UNL-CONICET, Predio CCT Conicet, Paraje El Pozo, 3000 Santa Fe, ArgentinaHere we present equilibrium data for the cross-metathesis of methyl oleate (MO) with cinnamaldehyde (CA) obtained experimentally from liquid-phase catalytic tests conducted at 323 K. The reaction was carried out in batch reactors, using different reactant molar ratios and the 2nd generation Ru Hoveyda-Grubbs complex as catalyst. Reaction mixtures at the equilibrium were analyzed by gas chromatography. Equilibrium constants were determined by assuming unitary activity coefficients for a cinnamaldehyde/methyl oleate equimolar ratio, and the validity of that approximation was evaluated by calculating the equilibrium conversions for different reactant molar ratios. Keywords: Equilibrium data, Cross-metathesis, Methyl oleate, Cinnamaldehyde, Fine chemistryhttp://www.sciencedirect.com/science/article/pii/S2352340918308436
collection DOAJ
language English
format Article
sources DOAJ
author Pablo D. Nieres
Andrés F. Trasarti
Carlos R. Apesteguía
spellingShingle Pablo D. Nieres
Andrés F. Trasarti
Carlos R. Apesteguía
Equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehyde
Data in Brief
author_facet Pablo D. Nieres
Andrés F. Trasarti
Carlos R. Apesteguía
author_sort Pablo D. Nieres
title Equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehyde
title_short Equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehyde
title_full Equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehyde
title_fullStr Equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehyde
title_full_unstemmed Equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehyde
title_sort equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehyde
publisher Elsevier
series Data in Brief
issn 2352-3409
publishDate 2018-10-01
description Here we present equilibrium data for the cross-metathesis of methyl oleate (MO) with cinnamaldehyde (CA) obtained experimentally from liquid-phase catalytic tests conducted at 323 K. The reaction was carried out in batch reactors, using different reactant molar ratios and the 2nd generation Ru Hoveyda-Grubbs complex as catalyst. Reaction mixtures at the equilibrium were analyzed by gas chromatography. Equilibrium constants were determined by assuming unitary activity coefficients for a cinnamaldehyde/methyl oleate equimolar ratio, and the validity of that approximation was evaluated by calculating the equilibrium conversions for different reactant molar ratios. Keywords: Equilibrium data, Cross-metathesis, Methyl oleate, Cinnamaldehyde, Fine chemistry
url http://www.sciencedirect.com/science/article/pii/S2352340918308436
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AT andresftrasarti equilibriumdataforthecrossmetathesisofmethyloleatewithcinnamaldehyde
AT carlosrapesteguia equilibriumdataforthecrossmetathesisofmethyloleatewithcinnamaldehyde
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