Equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehyde

Equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehyde

Here we present equilibrium data for the cross-metathesis of methyl oleate (MO) with cinnamaldehyde (CA) obtained experimentally from liquid-phase catalytic tests conducted at 323 K. The reaction was carried out in batch reactors, using different reactant molar ratios and the 2nd generation Ru Hovey...

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Bibliographic Details
Main Authors: Pablo D. Nieres, Andrés F. Trasarti, Carlos R. Apesteguía
Format: Article
Language:English
Published: Elsevier 2018-10-01
Series:Data in Brief
Online Access:http://www.sciencedirect.com/science/article/pii/S2352340918308436
Description
Summary:Here we present equilibrium data for the cross-metathesis of methyl oleate (MO) with cinnamaldehyde (CA) obtained experimentally from liquid-phase catalytic tests conducted at 323 K. The reaction was carried out in batch reactors, using different reactant molar ratios and the 2nd generation Ru Hoveyda-Grubbs complex as catalyst. Reaction mixtures at the equilibrium were analyzed by gas chromatography. Equilibrium constants were determined by assuming unitary activity coefficients for a cinnamaldehyde/methyl oleate equimolar ratio, and the validity of that approximation was evaluated by calculating the equilibrium conversions for different reactant molar ratios. Keywords: Equilibrium data, Cross-metathesis, Methyl oleate, Cinnamaldehyde, Fine chemistry
ISSN:2352-3409

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