Oxymatrinium tetrachloridoferrate(III)

Oxymatrinium tetrachloridoferrate(III)

The asymmetric unit of the title compound, (C15H25N2O2)[FeCl4], contains a tetrachloridoferrate(III) anion and a oxymatrinium cation [oxymatrine is (4R,7aS,13aR,13bR,13cS)-dodecahydro-1H,5H,10H-dipyrido[2,1-f:3′,2′,1′-ij][1,6]naphthyridin-10-one 4-oxide]. Th...

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Bibliographic Details
Main Authors: Xiong He, Xing Chuan Wei, Yu Chang Tian, Jia Xiong Lai
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812000281
Description
Summary:The asymmetric unit of the title compound, (C15H25N2O2)[FeCl4], contains a tetrachloridoferrate(III) anion and a oxymatrinium cation [oxymatrine is (4R,7aS,13aR,13bR,13cS)-dodecahydro-1H,5H,10H-dipyrido[2,1-f:3′,2′,1′-ij][1,6]naphthyridin-10-one 4-oxide]. The conformation of oxymatrine is similar to that of matrine with one ring having a half-chair conformation, while the others have chair conformations. Chiral chains of cations along the c axis are formed by O—H...O hydrogen bonds.
ISSN:1600-5368

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