N-[(3-Ethylphenyl)carbamothioyl]-2,2-diphenylacetamide
In the title molecule, C23H22N2OS, the diphenylacetyl and ethylbenzene groups adopt a trans–cis conformation, respectively, with respect to the S atom across the (S=)C—N bonds. This conformation is stabilized by an intramolecular N—H...O hydrogen bond and a weak C&#...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813014268 |
| Summary: | In the title molecule, C23H22N2OS, the diphenylacetyl and ethylbenzene groups adopt a trans–cis conformation, respectively, with respect to the S atom across the (S=)C—N bonds. This conformation is stabilized by an intramolecular N—H...O hydrogen bond and a weak C—H...S hydrogen bond. The ethyl-substituted benzene ring forms dihedral angles of 87.53 (15) and 73.94 (15)° with the phenyl rings. In the crystal, N—H...O hydrogen bonds link molecules into chains along [100]. A weak C—H...π interaction is also observed. |
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| ISSN: | 1600-5368 |