Mössbauer spectroscopy of reduced forms of a Fe-tetraphenylporphyrine complex

Mössbauer spectroscopy of reduced forms of a Fe-tetraphenylporphyrine complex

Molecular and electronic structure changes during successive reduction of a Fe-tetraphenylporphyrin chloride [Fe(III)(TPP):Cl] complex are reported on the basis of Mössbauer spectroscopy and DFT calculations. It is established that the attachment of additional electrons to a neutral Fe(III)(TPP):Cl...

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Bibliographic Details
Main Authors: Kaczmarzyk Tomasz, Rutkowska Iwona, Dziliński Kazimierz
Format: Article
Language:English
Published: Sciendo 2015-03-01
Series:Nukleonika
Subjects:
dft calculations
electronic structure
iron-(tetraphenyl)porphyrin
mössbauer spectroscopy
reduction process
Online Access:https://doi.org/10.1515/nuka-2015-0014

Internet

https://doi.org/10.1515/nuka-2015-0014

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