Crystal structure of 2,9-diphenyl-17λ6-thiatetracyclo[8.7.0.03,8.011,16]heptadeca-1(10),2,4,6,8,11(16),12,14-octaene-17,17-dione
The title compound, C28H18O2S, is composed of a naphthalene ring system fused with a benzothiophene ring and attached to two phenyl rings. The phenyl rings make dihedral angles of 70.92 (8) and 79.23 (8)° with the essentially planar naphthalene ring system (r.m.s. deviation = 0.031 Å). There is an...
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International Union of Crystallography
2014-09-01
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| Series: | Acta Crystallographica Section E |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814017838 |
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doaj-3735192dd6e745a780d8afc821d3bbfb2020-11-25T00:53:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-09-01709o1013o101410.1107/S1600536814017838su2758Crystal structure of 2,9-diphenyl-17λ6-thiatetracyclo[8.7.0.03,8.011,16]heptadeca-1(10),2,4,6,8,11(16),12,14-octaene-17,17-dioneS. Gopinath0P. Narayanan1K. Sethusankar2Meganathan Nandakumar3Arasambattu K. Mohanakrishnan4Department of Physics, RKM Vivekananda College (Autonomous), Chennai 600 004, IndiaDepartment of Physics, RKM Vivekananda College (Autonomous), Chennai 600 004, IndiaDepartment of Physics, RKM Vivekananda College (Autonomous), Chennai 600 004, IndiaDepartment of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, IndiaDepartment of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, IndiaThe title compound, C28H18O2S, is composed of a naphthalene ring system fused with a benzothiophene ring and attached to two phenyl rings. The phenyl rings make dihedral angles of 70.92 (8) and 79.23 (8)° with the essentially planar naphthalene ring system (r.m.s. deviation = 0.031 Å). There is an intramolecular C—H...π interaction present. In the crystal, molecules are linked by C—H...O hydrogen bonds which generate C(7) zigzag chains running parallel to [10-1]. The chains are linked via further C—H...π interactions, forming a three-dimensional structure.http://scripts.iucr.org/cgi-bin/paper?S1600536814017838crystal structurenaphthalenethiatetracycloheptadecaoctaenedione |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
S. Gopinath P. Narayanan K. Sethusankar Meganathan Nandakumar Arasambattu K. Mohanakrishnan |
| spellingShingle |
S. Gopinath P. Narayanan K. Sethusankar Meganathan Nandakumar Arasambattu K. Mohanakrishnan Crystal structure of 2,9-diphenyl-17λ6-thiatetracyclo[8.7.0.03,8.011,16]heptadeca-1(10),2,4,6,8,11(16),12,14-octaene-17,17-dione Acta Crystallographica Section E crystal structure naphthalene thiatetracyclo heptadeca octaenedione |
| author_facet |
S. Gopinath P. Narayanan K. Sethusankar Meganathan Nandakumar Arasambattu K. Mohanakrishnan |
| author_sort |
S. Gopinath |
| title |
Crystal structure of 2,9-diphenyl-17λ6-thiatetracyclo[8.7.0.03,8.011,16]heptadeca-1(10),2,4,6,8,11(16),12,14-octaene-17,17-dione |
| title_short |
Crystal structure of 2,9-diphenyl-17λ6-thiatetracyclo[8.7.0.03,8.011,16]heptadeca-1(10),2,4,6,8,11(16),12,14-octaene-17,17-dione |
| title_full |
Crystal structure of 2,9-diphenyl-17λ6-thiatetracyclo[8.7.0.03,8.011,16]heptadeca-1(10),2,4,6,8,11(16),12,14-octaene-17,17-dione |
| title_fullStr |
Crystal structure of 2,9-diphenyl-17λ6-thiatetracyclo[8.7.0.03,8.011,16]heptadeca-1(10),2,4,6,8,11(16),12,14-octaene-17,17-dione |
| title_full_unstemmed |
Crystal structure of 2,9-diphenyl-17λ6-thiatetracyclo[8.7.0.03,8.011,16]heptadeca-1(10),2,4,6,8,11(16),12,14-octaene-17,17-dione |
| title_sort |
crystal structure of 2,9-diphenyl-17λ6-thiatetracyclo[8.7.0.03,8.011,16]heptadeca-1(10),2,4,6,8,11(16),12,14-octaene-17,17-dione |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2014-09-01 |
| description |
The title compound, C28H18O2S, is composed of a naphthalene ring system fused with a benzothiophene ring and attached to two phenyl rings. The phenyl rings make dihedral angles of 70.92 (8) and 79.23 (8)° with the essentially planar naphthalene ring system (r.m.s. deviation = 0.031 Å). There is an intramolecular C—H...π interaction present. In the crystal, molecules are linked by C—H...O hydrogen bonds which generate C(7) zigzag chains running parallel to [10-1]. The chains are linked via further C—H...π interactions, forming a three-dimensional structure. |
| topic |
crystal structure naphthalene thiatetracyclo heptadeca octaenedione |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536814017838 |
| work_keys_str_mv |
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