A study of the drop size distributions and hold-up in short Kühni columns

• Main Authors: N. S. Oliveira, D. Moraes Silva, M. P. C. Gondim, M. Borges Mansur
• Format: Article
• Language: English
• Published: Brazilian Society of Chemical Engineering 2008-12-01
• Series: Brazilian Journal of Chemical Engineering
• Subjects: Liquid-liquid extraction; Kühni column; Hydrodynamics; Drop size distributions; Short columns
• Online Access: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322008000400010

The hydrodynamic behaviour of a short Kühni column was investigated under no mass transfer conditions using the binary system water (continuous phase) and Exxsol D-80 (dispersed phase). The counter-current flow pattern of the liquid phases was characterised regarding the Sauter mean drop diameter, drop size distribution and hold-up; a photographic method was used to assess drop sizes. The following operating variables were studied: rotor speed, flow rate of both liquid phases and column stage. The log-normal probability density function was found to be adequate to fit the experimental drop size distributions along the column. As expected, smaller drops and more uniform drop size distributions were obtained with the increase of rotor speed and column stage number, thus indicating the predominance of drop breakage phenomena in short columns. The total hold-up was influenced mainly by rotor speed and flow rate of the dispersed phase. Recommended correlations available in the literature were found to be inadequate for predicting experimental drop sizes and hold-up, so alternative expressions, valid only for short Kühni columns, were proposed.