Facile synthesis of palladium nanoparticles supported on urea-based porous organic polymers and its catalytic properties in Suzuki-Miyaura coupling

By using urea linked porous organic polymers as template, a new nano palladium catalyst with low Pd loading can be easily prepared (1.0 wt% Pd only). Although such less amount of Pd was contained in this new catalyst, it is still an effective catalyst for the Suzuki-Miyaura coupling of aryl iodines...

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Main Authors:	Pengwei Gao, Yongmei Xiao, Zhenhua Dong, Hongguo Pan, Wentao Wang
Format:	Article
Language:	English
Published:	Elsevier 2020-02-01
Series:	Journal of Saudi Chemical Society
Online Access:	http://www.sciencedirect.com/science/article/pii/S1319610319301140

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spelling	doaj-3647da8c060e43e1b5bfd3c31a62a6132020-11-25T02:14:51ZengElsevierJournal of Saudi Chemical Society1319-61032020-02-01242282287Facile synthesis of palladium nanoparticles supported on urea-based porous organic polymers and its catalytic properties in Suzuki-Miyaura couplingPengwei Gao0Yongmei Xiao1Zhenhua Dong2Hongguo Pan3Wentao Wang4College of Chemistry and Chemical Engineering, Henan University of Technology, Lianhua Street 100, Zhengzhou 450001, ChinaCollege of Chemistry and Chemical Engineering, Henan University of Technology, Lianhua Street 100, Zhengzhou 450001, ChinaCollege of Chemistry and Chemical Engineering, Henan University of Technology, Lianhua Street 100, Zhengzhou 450001, China; Corresponding authors.College of Chemistry and Chemical Engineering, Henan University of Technology, Lianhua Street 100, Zhengzhou 450001, ChinaDalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhongshan Road 457, Dalian 116023, China; Corresponding authors.By using urea linked porous organic polymers as template, a new nano palladium catalyst with low Pd loading can be easily prepared (1.0 wt% Pd only). Although such less amount of Pd was contained in this new catalyst, it is still an effective catalyst for the Suzuki-Miyaura coupling of aryl iodines and aryl boric acids, affording biphenyl products in excellent yields with outstandingly enhanced turnover numbers (up to 10,536) under green solvent (water). Keywords: Nanoparticles, Porous materials, Palladium, Porous organic polymers, Suzuki Cross couplinghttp://www.sciencedirect.com/science/article/pii/S1319610319301140
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Pengwei Gao Yongmei Xiao Zhenhua Dong Hongguo Pan Wentao Wang
spellingShingle	Pengwei Gao Yongmei Xiao Zhenhua Dong Hongguo Pan Wentao Wang Facile synthesis of palladium nanoparticles supported on urea-based porous organic polymers and its catalytic properties in Suzuki-Miyaura coupling Journal of Saudi Chemical Society
author_facet	Pengwei Gao Yongmei Xiao Zhenhua Dong Hongguo Pan Wentao Wang
author_sort	Pengwei Gao
title	Facile synthesis of palladium nanoparticles supported on urea-based porous organic polymers and its catalytic properties in Suzuki-Miyaura coupling
title_short	Facile synthesis of palladium nanoparticles supported on urea-based porous organic polymers and its catalytic properties in Suzuki-Miyaura coupling
title_full	Facile synthesis of palladium nanoparticles supported on urea-based porous organic polymers and its catalytic properties in Suzuki-Miyaura coupling
title_fullStr	Facile synthesis of palladium nanoparticles supported on urea-based porous organic polymers and its catalytic properties in Suzuki-Miyaura coupling
title_full_unstemmed	Facile synthesis of palladium nanoparticles supported on urea-based porous organic polymers and its catalytic properties in Suzuki-Miyaura coupling
title_sort	facile synthesis of palladium nanoparticles supported on urea-based porous organic polymers and its catalytic properties in suzuki-miyaura coupling
publisher	Elsevier
series	Journal of Saudi Chemical Society
issn	1319-6103
publishDate	2020-02-01
description	By using urea linked porous organic polymers as template, a new nano palladium catalyst with low Pd loading can be easily prepared (1.0 wt% Pd only). Although such less amount of Pd was contained in this new catalyst, it is still an effective catalyst for the Suzuki-Miyaura coupling of aryl iodines and aryl boric acids, affording biphenyl products in excellent yields with outstandingly enhanced turnover numbers (up to 10,536) under green solvent (water). Keywords: Nanoparticles, Porous materials, Palladium, Porous organic polymers, Suzuki Cross coupling
url	http://www.sciencedirect.com/science/article/pii/S1319610319301140
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Facile synthesis of palladium nanoparticles supported on urea-based porous organic polymers and its catalytic properties in Suzuki-Miyaura coupling

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