2-((1E)-1-{2-[(2Z)-4-(4-Bromophenyl)-3-phenyl-2,3-dihydro-1,3-thiazol-2-ylidene]hydrazin-1-ylidene}ethyl)pyridin-1-ium bromide monohydrate

2-((1E)-1-{2-[(2Z)-4-(4-Bromophenyl)-3-phenyl-2,3-dihydro-1,3-thiazol-2-ylidene]hydrazin-1-ylidene}ethyl)pyridin-1-ium bromide monohydrate

In the title hydrated molecular salt, C22H18BrN4S+·Br−·H2O, the aromatic rings make dihedral angles of 14.20 (12), 34.29 (10) and 68.75 (11)° with the thiazole ring. In the crystal, molecules are linked into chains running parallel to the a axis by association of the bromide ions and the water molec...

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Main Authors: Joel T. Mague, Shaaban K. Mohamed, Mehmet Akkurt, Ahmed T. Abd El-Alaziz, Mustafa R. Albayati
Format: Article
Language:English
Published: International Union of Crystallography 2014-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681400347X
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spelling doaj-35f9495177e54e59bc9fdf3145cd56f72020-11-24T21:28:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-03-01703o328o32910.1107/S160053681400347Xqm21042-((1E)-1-{2-[(2Z)-4-(4-Bromophenyl)-3-phenyl-2,3-dihydro-1,3-thiazol-2-ylidene]hydrazin-1-ylidene}ethyl)pyridin-1-ium bromide monohydrateJoel T. Mague0Shaaban K. Mohamed1Mehmet Akkurt2Ahmed T. Abd El-Alaziz3Mustafa R. Albayati4Department of Chemistry, Tulane University, New Orleans, LA 70118, USAChemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, EnglandDepartment of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, TurkeyChemistry Department, Faculty of Science, Minia University, 61519 El-Minia, EgyptKirkuk University, College of Science, Department of Chemistry, Kirkuk, IraqIn the title hydrated molecular salt, C22H18BrN4S+·Br−·H2O, the aromatic rings make dihedral angles of 14.20 (12), 34.29 (10) and 68.75 (11)° with the thiazole ring. In the crystal, molecules are linked into chains running parallel to the a axis by association of the bromide ions and the water molecules of crystallization with the cations via N—H...O, O—H...Br, C—H...N and C—H...Br hydrogen-bonding interactions. C—H...π and C—Br...π [3.7426 (11) Å, 161.73 (7)°] interactions are also observed, forming infinite chains extending along the b-axis direction.http://scripts.iucr.org/cgi-bin/paper?S160053681400347X
collection DOAJ
language English
format Article
sources DOAJ
author Joel T. Mague
Shaaban K. Mohamed
Mehmet Akkurt
Ahmed T. Abd El-Alaziz
Mustafa R. Albayati
spellingShingle Joel T. Mague
Shaaban K. Mohamed
Mehmet Akkurt
Ahmed T. Abd El-Alaziz
Mustafa R. Albayati
2-((1E)-1-{2-[(2Z)-4-(4-Bromophenyl)-3-phenyl-2,3-dihydro-1,3-thiazol-2-ylidene]hydrazin-1-ylidene}ethyl)pyridin-1-ium bromide monohydrate
Acta Crystallographica Section E
author_facet Joel T. Mague
Shaaban K. Mohamed
Mehmet Akkurt
Ahmed T. Abd El-Alaziz
Mustafa R. Albayati
author_sort Joel T. Mague
title 2-((1E)-1-{2-[(2Z)-4-(4-Bromophenyl)-3-phenyl-2,3-dihydro-1,3-thiazol-2-ylidene]hydrazin-1-ylidene}ethyl)pyridin-1-ium bromide monohydrate
title_short 2-((1E)-1-{2-[(2Z)-4-(4-Bromophenyl)-3-phenyl-2,3-dihydro-1,3-thiazol-2-ylidene]hydrazin-1-ylidene}ethyl)pyridin-1-ium bromide monohydrate
title_full 2-((1E)-1-{2-[(2Z)-4-(4-Bromophenyl)-3-phenyl-2,3-dihydro-1,3-thiazol-2-ylidene]hydrazin-1-ylidene}ethyl)pyridin-1-ium bromide monohydrate
title_fullStr 2-((1E)-1-{2-[(2Z)-4-(4-Bromophenyl)-3-phenyl-2,3-dihydro-1,3-thiazol-2-ylidene]hydrazin-1-ylidene}ethyl)pyridin-1-ium bromide monohydrate
title_full_unstemmed 2-((1E)-1-{2-[(2Z)-4-(4-Bromophenyl)-3-phenyl-2,3-dihydro-1,3-thiazol-2-ylidene]hydrazin-1-ylidene}ethyl)pyridin-1-ium bromide monohydrate
title_sort 2-((1e)-1-{2-[(2z)-4-(4-bromophenyl)-3-phenyl-2,3-dihydro-1,3-thiazol-2-ylidene]hydrazin-1-ylidene}ethyl)pyridin-1-ium bromide monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-03-01
description In the title hydrated molecular salt, C22H18BrN4S+·Br−·H2O, the aromatic rings make dihedral angles of 14.20 (12), 34.29 (10) and 68.75 (11)° with the thiazole ring. In the crystal, molecules are linked into chains running parallel to the a axis by association of the bromide ions and the water molecules of crystallization with the cations via N—H...O, O—H...Br, C—H...N and C—H...Br hydrogen-bonding interactions. C—H...π and C—Br...π [3.7426 (11) Å, 161.73 (7)°] interactions are also observed, forming infinite chains extending along the b-axis direction.
url http://scripts.iucr.org/cgi-bin/paper?S160053681400347X
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AT shaabankmohamed 21e122z44bromophenyl3phenyl23dihydro13thiazol2ylidenehydrazin1ylideneethylpyridin1iumbromidemonohydrate
AT mehmetakkurt 21e122z44bromophenyl3phenyl23dihydro13thiazol2ylidenehydrazin1ylideneethylpyridin1iumbromidemonohydrate
AT ahmedtabdelalaziz 21e122z44bromophenyl3phenyl23dihydro13thiazol2ylidenehydrazin1ylideneethylpyridin1iumbromidemonohydrate
AT mustafaralbayati 21e122z44bromophenyl3phenyl23dihydro13thiazol2ylidenehydrazin1ylideneethylpyridin1iumbromidemonohydrate
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