trans-Dichloridotetrapyrazineruthenium(II) dichloromethane disolvate

trans-Dichloridotetrapyrazineruthenium(II) dichloromethane disolvate

In the title compound, [RuCl2(C4H4N2)4]·2CH2Cl2, the RuII atom occupies a position of 222 symmetry and the C atom of the solvent molecule occupies a site with twofold symmetry. The RuII atom has a slightly distorted octahedral geometry. The pyrazine rings are propeller-like and rotated...

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Main Authors: Vladimir N. Nesterov, Wajiha Khan, Alexandra E. Rangel, Bradley W. Smucker
Format: Article
Language:English
Published: International Union of Crystallography 2012-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812035817
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spelling doaj-35cae7bc494849c39b7994298cb7aca12020-11-24T22:09:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-09-01689m1193m119310.1107/S1600536812035817trans-Dichloridotetrapyrazineruthenium(II) dichloromethane disolvateVladimir N. NesterovWajiha KhanAlexandra E. RangelBradley W. SmuckerIn the title compound, [RuCl2(C4H4N2)4]·2CH2Cl2, the RuII atom occupies a position of 222 symmetry and the C atom of the solvent molecule occupies a site with twofold symmetry. The RuII atom has a slightly distorted octahedral geometry. The pyrazine rings are propeller-like and rotated 45.1 (1)° from the RuN4 plane. In the crystal, the complex and solvent molecules are bridged by weak C—H...N hydrogen bonds along the c axis. Weak intermolecular C—H...Cl contacts link the complexes in the ab plane, forming a network.http://scripts.iucr.org/cgi-bin/paper?S1600536812035817
collection DOAJ
language English
format Article
sources DOAJ
author Vladimir N. Nesterov
Wajiha Khan
Alexandra E. Rangel
Bradley W. Smucker
spellingShingle Vladimir N. Nesterov
Wajiha Khan
Alexandra E. Rangel
Bradley W. Smucker
trans-Dichloridotetrapyrazineruthenium(II) dichloromethane disolvate
Acta Crystallographica Section E
author_facet Vladimir N. Nesterov
Wajiha Khan
Alexandra E. Rangel
Bradley W. Smucker
author_sort Vladimir N. Nesterov
title trans-Dichloridotetrapyrazineruthenium(II) dichloromethane disolvate
title_short trans-Dichloridotetrapyrazineruthenium(II) dichloromethane disolvate
title_full trans-Dichloridotetrapyrazineruthenium(II) dichloromethane disolvate
title_fullStr trans-Dichloridotetrapyrazineruthenium(II) dichloromethane disolvate
title_full_unstemmed trans-Dichloridotetrapyrazineruthenium(II) dichloromethane disolvate
title_sort trans-dichloridotetrapyrazineruthenium(ii) dichloromethane disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-09-01
description In the title compound, [RuCl2(C4H4N2)4]·2CH2Cl2, the RuII atom occupies a position of 222 symmetry and the C atom of the solvent molecule occupies a site with twofold symmetry. The RuII atom has a slightly distorted octahedral geometry. The pyrazine rings are propeller-like and rotated 45.1 (1)° from the RuN4 plane. In the crystal, the complex and solvent molecules are bridged by weak C—H...N hydrogen bonds along the c axis. Weak intermolecular C—H...Cl contacts link the complexes in the ab plane, forming a network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812035817
work_keys_str_mv AT vladimirnnesterov transdichloridotetrapyrazinerutheniumiidichloromethanedisolvate
AT wajihakhan transdichloridotetrapyrazinerutheniumiidichloromethanedisolvate
AT alexandraerangel transdichloridotetrapyrazinerutheniumiidichloromethanedisolvate
AT bradleywsmucker transdichloridotetrapyrazinerutheniumiidichloromethanedisolvate
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