1-[(E)-(2-Phenoxyanilino)methylene]naphthalen-2(1H)-one

1-[(E)-(2-Phenoxyanilino)methylene]naphthalen-2(1H)-one

The molecule of the title compound, C23H17NO2, a Schiff base derived from 2-hydroxy-1-naphthaldehyde, crystallizes in the keto–amine tautomeric form. The dihedral angle between the aniline and hydroxybenzene rings is 77.41 (17)°, whereas the planes of the nap...

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Main Authors: Ersin Temel, Erbil Ağar, Orhan Büyükgüngör
Format: Article
Language:English
Published: International Union of Crystallography 2010-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810013851
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spelling doaj-34ef2afcf0fb48efac7b8cb6505256f22020-11-25T00:57:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-05-01665o1131o113110.1107/S16005368100138511-[(E)-(2-Phenoxyanilino)methylene]naphthalen-2(1H)-oneErsin TemelErbil AğarOrhan BüyükgüngörThe molecule of the title compound, C23H17NO2, a Schiff base derived from 2-hydroxy-1-naphthaldehyde, crystallizes in the keto–amine tautomeric form. The dihedral angle between the aniline and hydroxybenzene rings is 77.41 (17)°, whereas the planes of the naphthaldehyde and fused aniline benzene rings are nearly coplanar, making a dihedral angle of 8.29 (15)°. Intramolecular N—H...O hydrogen bonding, a characteristic hydrogen bond for Schiff bases, helps to stabilize the molecular structure. Weak intermolecular C—H...π interactions are present in the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536810013851
collection DOAJ
language English
format Article
sources DOAJ
author Ersin Temel
Erbil Ağar
Orhan Büyükgüngör
spellingShingle Ersin Temel
Erbil Ağar
Orhan Büyükgüngör
1-[(E)-(2-Phenoxyanilino)methylene]naphthalen-2(1H)-one
Acta Crystallographica Section E
author_facet Ersin Temel
Erbil Ağar
Orhan Büyükgüngör
author_sort Ersin Temel
title 1-[(E)-(2-Phenoxyanilino)methylene]naphthalen-2(1H)-one
title_short 1-[(E)-(2-Phenoxyanilino)methylene]naphthalen-2(1H)-one
title_full 1-[(E)-(2-Phenoxyanilino)methylene]naphthalen-2(1H)-one
title_fullStr 1-[(E)-(2-Phenoxyanilino)methylene]naphthalen-2(1H)-one
title_full_unstemmed 1-[(E)-(2-Phenoxyanilino)methylene]naphthalen-2(1H)-one
title_sort 1-[(e)-(2-phenoxyanilino)methylene]naphthalen-2(1h)-one
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-05-01
description The molecule of the title compound, C23H17NO2, a Schiff base derived from 2-hydroxy-1-naphthaldehyde, crystallizes in the keto–amine tautomeric form. The dihedral angle between the aniline and hydroxybenzene rings is 77.41 (17)°, whereas the planes of the naphthaldehyde and fused aniline benzene rings are nearly coplanar, making a dihedral angle of 8.29 (15)°. Intramolecular N—H...O hydrogen bonding, a characteristic hydrogen bond for Schiff bases, helps to stabilize the molecular structure. Weak intermolecular C—H...π interactions are present in the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810013851
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AT erbilaamp287ar 1e2phenoxyanilinomethylenenaphthalen21hone
AT orhanbamp252yamp252kgamp252ngamp246r 1e2phenoxyanilinomethylenenaphthalen21hone
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