Design of CNS-Li₂SiO₃ Permeable Protective Coatings and Effects on Mortar Matrix

• Main Authors: Xu Li, Chonggen Pan, Dong Li, Jian Geng, Na Chen, Jingzi He, Shuhua Liu
• Format: Article
• Language: English
• Published: MDPI AG 2020-04-01
• Series: Materials
• Subjects: lithium silicate; colloidal nano-silica; protective coatings; mortar; microstructure
• Online Access: https://www.mdpi.com/1996-1944/13/7/1733

In this paper, we prepared permeable protective coatings composed of lithium silicate (Li₂SiO₃), where the coating was modified by colloidal nano-silica (CNS). Three levels of lithium silicate (i.e., 30 wt. %; 40 wt. %; 50 wt. %), sodium silicate (i.e., 5 wt. %; 10 wt. %; 15 wt. %), and surfactant (i.e., 0.05 wt. %; 0.1 wt. %; 0.15 wt. %) were involved in this study. An orthogonal experiment design selected the optimal proportion basedon thestrength and water absorption requirements of mortar. The effects of CNS-Li₂SiO₃ coating on the resistance to permeability of chloride ions and carbonation of specimens were also studied. The outcomes were interpreted using scanning electron microscopy (SEM), X-ray diffraction (XRD), and mercury intrusion porosimetry (MIP) techniques. The results showed that the optimum mix formulation consisted of 40 wt. % of lithium silicate, 10 wt. % of sodium silicate and 0.1 wt. % of surfactant within the mixtures investigated. Meanwhile, compared tothe control group, after the specimens were coated at 21 days curing age of mortar, the strength development, 48-h water absorption, resistance to chloride ions penetration, and carbonation of CNS-Li₂SiO₃ coated specimenswere improved. This could be attributed to the second hydration, leading to a reduction of the content of Ca(OH)₂ and an increase of the amount of C–S–H gel within specimens. Thus, the microstructure of mortar matrix was improved after coated with CNS-Li₂SiO₃ permeable protective coatings.