(18-Crown-6)(trifluoromethanesulfonato)sodium

(18-Crown-6)(trifluoromethanesulfonato)sodium

The title compound, [Na(CF3O3S)(C12H24O6)], features a sodium cation that is coordinated by eight O atoms in an irregular hexagonal bipyramidal environment. The equatorial positions are occupied by the six O atoms of an 18-crown-6 ether ring. In the axial positions, there is one O atom of a trifluor...

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Main Authors: Hien Ngoc Phan, Hans-Wolfram Lerner, Michael Bolte
Format: Article
Language:English
Published: International Union of Crystallography 2010-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810025961
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spelling doaj-34b9ab7884574cffb8352283063b5edb2020-11-25T01:27:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m893m89310.1107/S1600536810025961(18-Crown-6)(trifluoromethanesulfonato)sodiumHien Ngoc PhanHans-Wolfram LernerMichael BolteThe title compound, [Na(CF3O3S)(C12H24O6)], features a sodium cation that is coordinated by eight O atoms in an irregular hexagonal bipyramidal environment. The equatorial positions are occupied by the six O atoms of an 18-crown-6 ether ring. In the axial positions, there is one O atom of a trifluoromethanesulfonate anion and an ether O atom of a symmetry-equivalent crown ether ring. In this way, centrosymmetric dimers are formed. http://scripts.iucr.org/cgi-bin/paper?S1600536810025961
collection DOAJ
language English
format Article
sources DOAJ
author Hien Ngoc Phan
Hans-Wolfram Lerner
Michael Bolte
spellingShingle Hien Ngoc Phan
Hans-Wolfram Lerner
Michael Bolte
(18-Crown-6)(trifluoromethanesulfonato)sodium
Acta Crystallographica Section E
author_facet Hien Ngoc Phan
Hans-Wolfram Lerner
Michael Bolte
author_sort Hien Ngoc Phan
title (18-Crown-6)(trifluoromethanesulfonato)sodium
title_short (18-Crown-6)(trifluoromethanesulfonato)sodium
title_full (18-Crown-6)(trifluoromethanesulfonato)sodium
title_fullStr (18-Crown-6)(trifluoromethanesulfonato)sodium
title_full_unstemmed (18-Crown-6)(trifluoromethanesulfonato)sodium
title_sort (18-crown-6)(trifluoromethanesulfonato)sodium
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-08-01
description The title compound, [Na(CF3O3S)(C12H24O6)], features a sodium cation that is coordinated by eight O atoms in an irregular hexagonal bipyramidal environment. The equatorial positions are occupied by the six O atoms of an 18-crown-6 ether ring. In the axial positions, there is one O atom of a trifluoromethanesulfonate anion and an ether O atom of a symmetry-equivalent crown ether ring. In this way, centrosymmetric dimers are formed.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810025961
work_keys_str_mv AT hienngocphan 18crown6trifluoromethanesulfonatosodium
AT hanswolframlerner 18crown6trifluoromethanesulfonatosodium
AT michaelbolte 18crown6trifluoromethanesulfonatosodium
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