Synthesis, sintering, specific heat and magnetism of Eu3S4 by low-temperature CS2-gas sulfurization of Eu2O3 nanospheres

• Main Authors: Chen Yuqi, Li Liang, Hirai Shinji
• Format: Article
• Language: English
• Published: Sciendo 2018-12-01
• Series: Materials Science-Poland
• Subjects: eu3s4; mixed-valence compound; inhomogeneous compound; cs2-gas sulfurization; specific heat; magnetic properties
• Online Access: https://doi.org/10.2478/msp-2018-0097

Single-phase Eu3S4 was obtained via CS2 gas sulfurization of Eu2O3 nanospheres at 773 K for longer than 0.5 h. The primary particle size of Eu3S4 became larger than that of Eu2O3 during the sulfurization process. Pure synthetic Eu3S4 powders were unstable and transformed to EuS at 873 K under vacuum. Eu3S4 compacts were sintered in temperature range of 773 K to 1173 K and they transformed to EuS at 1473 K during spark plasma sintering. Specific heat of sintered Eu3S4 did not show an anomalous behavior in the range of 2 K to 50 K. The magnetic susceptibility of polycrystalline Eu3S4 followed a Curie-Weiss law from 2 K to 300 K. Magnetization of polycrystalline Eu3S4 was larger than that of single crystal Eu3S4 when the magnetic field was less than 3.5 kOe.