Thermochemical properties and regularities of amides, anilides, and amidic acids
The thermodynamic properties of carbamide and its alkyl substituted were studied insufficiently. In this article, the enthalpies of combustion of ΔсН of some amides, anilides and amidic acids have been determined experimentally; their standard enthalpies of formation have been calculated. Linear dep...
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doaj-34a4ed9928c2451abe586d72f81633812020-11-25T01:28:54ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552018-03-0165112713010.17344/acsi.2017.3683557Thermochemical properties and regularities of amides, anilides, and amidic acidsAlma Kairlapovna Ryskaliyeva0Murat Ergalievich Baltabayev1Aigul Moldakhmetovna Zhubatova2Kazakh National Agrarian UniversityKazakh National Agrarian UniversityKazakh National Agrarian UniversityThe thermodynamic properties of carbamide and its alkyl substituted were studied insufficiently. In this article, the enthalpies of combustion of ΔсН of some amides, anilides and amidic acids have been determined experimentally; their standard enthalpies of formation have been calculated. Linear dependences between the average atomic enthalpy of combustion of ΔcH amides and their basicity constants in acidic aqueous solutions of pKBH+have been established; a correlation that relates the enthalpies of combustion of amides and the corresponding amidic acids has been found.https://journals.matheo.si/index.php/ACSi/article/view/3683enthalpy of combustionthermochemistryamidescorrelation analysis |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Alma Kairlapovna Ryskaliyeva Murat Ergalievich Baltabayev Aigul Moldakhmetovna Zhubatova |
spellingShingle |
Alma Kairlapovna Ryskaliyeva Murat Ergalievich Baltabayev Aigul Moldakhmetovna Zhubatova Thermochemical properties and regularities of amides, anilides, and amidic acids Acta Chimica Slovenica enthalpy of combustion thermochemistry amides correlation analysis |
author_facet |
Alma Kairlapovna Ryskaliyeva Murat Ergalievich Baltabayev Aigul Moldakhmetovna Zhubatova |
author_sort |
Alma Kairlapovna Ryskaliyeva |
title |
Thermochemical properties and regularities of amides, anilides, and amidic acids |
title_short |
Thermochemical properties and regularities of amides, anilides, and amidic acids |
title_full |
Thermochemical properties and regularities of amides, anilides, and amidic acids |
title_fullStr |
Thermochemical properties and regularities of amides, anilides, and amidic acids |
title_full_unstemmed |
Thermochemical properties and regularities of amides, anilides, and amidic acids |
title_sort |
thermochemical properties and regularities of amides, anilides, and amidic acids |
publisher |
Slovenian Chemical Society |
series |
Acta Chimica Slovenica |
issn |
1318-0207 1580-3155 |
publishDate |
2018-03-01 |
description |
The thermodynamic properties of carbamide and its alkyl substituted were studied insufficiently. In this article, the enthalpies of combustion of ΔсН of some amides, anilides and amidic acids have been determined experimentally; their standard enthalpies of formation have been calculated. Linear dependences between the average atomic enthalpy of combustion of ΔcH amides and their basicity constants in acidic aqueous solutions of pKBH+have been established; a correlation that relates the enthalpies of combustion of amides and the corresponding amidic acids has been found. |
topic |
enthalpy of combustion thermochemistry amides correlation analysis |
url |
https://journals.matheo.si/index.php/ACSi/article/view/3683 |
work_keys_str_mv |
AT almakairlapovnaryskaliyeva thermochemicalpropertiesandregularitiesofamidesanilidesandamidicacids AT muratergalievichbaltabayev thermochemicalpropertiesandregularitiesofamidesanilidesandamidicacids AT aigulmoldakhmetovnazhubatova thermochemicalpropertiesandregularitiesofamidesanilidesandamidicacids |
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1725099581970055168 |