Thermochemical properties and regularities of amides, anilides, and amidic acids

The thermodynamic properties of carbamide and its alkyl substituted were studied insufficiently. In this article, the enthalpies of combustion of ΔсН of some amides, anilides and amidic acids have been determined experimentally; their standard enthalpies of formation have been calculated. Linear dep...

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Main Authors: Alma Kairlapovna Ryskaliyeva, Murat Ergalievich Baltabayev, Aigul Moldakhmetovna Zhubatova
Format: Article
Language:English
Published: Slovenian Chemical Society 2018-03-01
Series:Acta Chimica Slovenica
Subjects:
Online Access:https://journals.matheo.si/index.php/ACSi/article/view/3683
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spelling doaj-34a4ed9928c2451abe586d72f81633812020-11-25T01:28:54ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552018-03-0165112713010.17344/acsi.2017.3683557Thermochemical properties and regularities of amides, anilides, and amidic acidsAlma Kairlapovna Ryskaliyeva0Murat Ergalievich Baltabayev1Aigul Moldakhmetovna Zhubatova2Kazakh National Agrarian UniversityKazakh National Agrarian UniversityKazakh National Agrarian UniversityThe thermodynamic properties of carbamide and its alkyl substituted were studied insufficiently. In this article, the enthalpies of combustion of ΔсН of some amides, anilides and amidic acids have been determined experimentally; their standard enthalpies of formation have been calculated. Linear dependences between the average atomic enthalpy of combustion of ΔcH amides and their basicity constants in acidic aqueous solutions of pKBH+have been established; a correlation that relates the enthalpies of combustion of amides and the corresponding amidic acids has been found.https://journals.matheo.si/index.php/ACSi/article/view/3683enthalpy of combustionthermochemistryamidescorrelation analysis
collection DOAJ
language English
format Article
sources DOAJ
author Alma Kairlapovna Ryskaliyeva
Murat Ergalievich Baltabayev
Aigul Moldakhmetovna Zhubatova
spellingShingle Alma Kairlapovna Ryskaliyeva
Murat Ergalievich Baltabayev
Aigul Moldakhmetovna Zhubatova
Thermochemical properties and regularities of amides, anilides, and amidic acids
Acta Chimica Slovenica
enthalpy of combustion
thermochemistry
amides
correlation analysis
author_facet Alma Kairlapovna Ryskaliyeva
Murat Ergalievich Baltabayev
Aigul Moldakhmetovna Zhubatova
author_sort Alma Kairlapovna Ryskaliyeva
title Thermochemical properties and regularities of amides, anilides, and amidic acids
title_short Thermochemical properties and regularities of amides, anilides, and amidic acids
title_full Thermochemical properties and regularities of amides, anilides, and amidic acids
title_fullStr Thermochemical properties and regularities of amides, anilides, and amidic acids
title_full_unstemmed Thermochemical properties and regularities of amides, anilides, and amidic acids
title_sort thermochemical properties and regularities of amides, anilides, and amidic acids
publisher Slovenian Chemical Society
series Acta Chimica Slovenica
issn 1318-0207
1580-3155
publishDate 2018-03-01
description The thermodynamic properties of carbamide and its alkyl substituted were studied insufficiently. In this article, the enthalpies of combustion of ΔсН of some amides, anilides and amidic acids have been determined experimentally; their standard enthalpies of formation have been calculated. Linear dependences between the average atomic enthalpy of combustion of ΔcH amides and their basicity constants in acidic aqueous solutions of pKBH+have been established; a correlation that relates the enthalpies of combustion of amides and the corresponding amidic acids has been found.
topic enthalpy of combustion
thermochemistry
amides
correlation analysis
url https://journals.matheo.si/index.php/ACSi/article/view/3683
work_keys_str_mv AT almakairlapovnaryskaliyeva thermochemicalpropertiesandregularitiesofamidesanilidesandamidicacids
AT muratergalievichbaltabayev thermochemicalpropertiesandregularitiesofamidesanilidesandamidicacids
AT aigulmoldakhmetovnazhubatova thermochemicalpropertiesandregularitiesofamidesanilidesandamidicacids
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