Case study on thermal impact of novel corrosion inhibitor on mild steel

Just a few investigations have studied the function of various temperatures in distribution system mild steel corrosion. Generally, increasing temperatures caused the accelerated corrosion of mild steel. In addition, the average of chemical processes were increased as the temperatures were increased...

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Main Authors: Hussein Jwad Habeeb, Hasan Mohammed Luaibi, Thamer Adnan Abdullah, Rifaat Mohammed Dakhil, Abdul Amir H. Kadhum, Ahmed A. Al-Amiery
Format: Article
Language:English
Published: Elsevier 2018-09-01
Series:Case Studies in Thermal Engineering
Online Access:http://www.sciencedirect.com/science/article/pii/S2214157X17303167
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spelling doaj-347e99b71a70481ab46d18f0a319ed9f2020-11-24T23:24:32ZengElsevierCase Studies in Thermal Engineering2214-157X2018-09-01126468Case study on thermal impact of novel corrosion inhibitor on mild steelHussein Jwad Habeeb0Hasan Mohammed Luaibi1Thamer Adnan Abdullah2Rifaat Mohammed Dakhil3Abdul Amir H. Kadhum4Ahmed A. Al-Amiery5Department of Chemical & Process Engineering, Faculty of Engineering & Built Environment, Universiti Kebangsaan Malaysia, Bangi, Selangor 43600, MalaysiaDepartment of Chemistry, College of Science, Al-Qadisiyah University, Al-Dewaniyah, IraqBranch of Applied Chemistry, Applied Science Department, University of Technology, Baghdad, IraqTechnical College Basra, Southern Technical University, IraqDepartment of Chemical & Process Engineering, Faculty of Engineering & Built Environment, Universiti Kebangsaan Malaysia, Bangi, Selangor 43600, MalaysiaEnergy and Renewable Energies Technology Center, University of Technology, Baghdad 10001, Iraq; Correspondence author.Just a few investigations have studied the function of various temperatures in distribution system mild steel corrosion. Generally, increasing temperatures caused the accelerated corrosion of mild steel. In addition, the average of chemical processes were increased as the temperatures were increased regarding to Arrhenius' Law. The synthesis and characterization of a novel organic corrosion inhibitor 4-(((5-ethyl-1,3,4-thiadiazol-2-yl) imino) methyl) phenol, for mild steel in hydrochloric acid was successfully reported for the first time. This inhibitor is tested as corrosion inhibitor on a mild steel sample MS in 1 M hydrochloric acid solution using Potentio-dynamics (PD) and Electrochemical Frequency Modulation (EFM) method. The results obtained indicate that inhibitor acts as an excellent corrosion inhibitor for mild steel sample in HCl solution with efficiency above 90%. Changes in the results parameters suggested adsorption on the surface of mild steel sample, which it leading to the formation of protective coating layer. However, this protective layer becomes weak when the temperature of the solution increases. Keywords: 4-(((5-Ethyl-1,3,4-thiadiazol-2-yl) imino) methyl) phenol, Mild steel, Corrosion inhibitor, Potentio-dynamics (PD)http://www.sciencedirect.com/science/article/pii/S2214157X17303167
collection DOAJ
language English
format Article
sources DOAJ
author Hussein Jwad Habeeb
Hasan Mohammed Luaibi
Thamer Adnan Abdullah
Rifaat Mohammed Dakhil
Abdul Amir H. Kadhum
Ahmed A. Al-Amiery
spellingShingle Hussein Jwad Habeeb
Hasan Mohammed Luaibi
Thamer Adnan Abdullah
Rifaat Mohammed Dakhil
Abdul Amir H. Kadhum
Ahmed A. Al-Amiery
Case study on thermal impact of novel corrosion inhibitor on mild steel
Case Studies in Thermal Engineering
author_facet Hussein Jwad Habeeb
Hasan Mohammed Luaibi
Thamer Adnan Abdullah
Rifaat Mohammed Dakhil
Abdul Amir H. Kadhum
Ahmed A. Al-Amiery
author_sort Hussein Jwad Habeeb
title Case study on thermal impact of novel corrosion inhibitor on mild steel
title_short Case study on thermal impact of novel corrosion inhibitor on mild steel
title_full Case study on thermal impact of novel corrosion inhibitor on mild steel
title_fullStr Case study on thermal impact of novel corrosion inhibitor on mild steel
title_full_unstemmed Case study on thermal impact of novel corrosion inhibitor on mild steel
title_sort case study on thermal impact of novel corrosion inhibitor on mild steel
publisher Elsevier
series Case Studies in Thermal Engineering
issn 2214-157X
publishDate 2018-09-01
description Just a few investigations have studied the function of various temperatures in distribution system mild steel corrosion. Generally, increasing temperatures caused the accelerated corrosion of mild steel. In addition, the average of chemical processes were increased as the temperatures were increased regarding to Arrhenius' Law. The synthesis and characterization of a novel organic corrosion inhibitor 4-(((5-ethyl-1,3,4-thiadiazol-2-yl) imino) methyl) phenol, for mild steel in hydrochloric acid was successfully reported for the first time. This inhibitor is tested as corrosion inhibitor on a mild steel sample MS in 1 M hydrochloric acid solution using Potentio-dynamics (PD) and Electrochemical Frequency Modulation (EFM) method. The results obtained indicate that inhibitor acts as an excellent corrosion inhibitor for mild steel sample in HCl solution with efficiency above 90%. Changes in the results parameters suggested adsorption on the surface of mild steel sample, which it leading to the formation of protective coating layer. However, this protective layer becomes weak when the temperature of the solution increases. Keywords: 4-(((5-Ethyl-1,3,4-thiadiazol-2-yl) imino) methyl) phenol, Mild steel, Corrosion inhibitor, Potentio-dynamics (PD)
url http://www.sciencedirect.com/science/article/pii/S2214157X17303167
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