Bis(triphenylphosphoranylidene)ammonium iodide
The title compound, C36H30NP2+·I−, was obtained accidently from crystallization of a reaction mixture containing [(Ph3P)2N]OH and B(OH)3, which was contaminated with MeI. There are two independent [(Ph3P)2N]+ cations and two I− anions within the asymmetric un...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-02-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810000267 |
| id |
doaj-34168dfc68764f61a7a29c917d8ab846 |
|---|---|
| record_format |
Article |
| spelling |
doaj-34168dfc68764f61a7a29c917d8ab8462020-11-25T01:56:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662o319o31910.1107/S1600536810000267Bis(triphenylphosphoranylidene)ammonium iodideMichael A. BeckettPeter N. HortonMichael B. HursthouseJames L. TimmisThe title compound, C36H30NP2+·I−, was obtained accidently from crystallization of a reaction mixture containing [(Ph3P)2N]OH and B(OH)3, which was contaminated with MeI. There are two independent [(Ph3P)2N]+ cations and two I− anions within the asymmetric unit. The central PNP angles are non-linear [137.6 (2) and 134.4 (2)°] and the phenyl substituents on P centres adopt different conformations within these two cations. http://scripts.iucr.org/cgi-bin/paper?S1600536810000267 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Michael A. Beckett Peter N. Horton Michael B. Hursthouse James L. Timmis |
| spellingShingle |
Michael A. Beckett Peter N. Horton Michael B. Hursthouse James L. Timmis Bis(triphenylphosphoranylidene)ammonium iodide Acta Crystallographica Section E |
| author_facet |
Michael A. Beckett Peter N. Horton Michael B. Hursthouse James L. Timmis |
| author_sort |
Michael A. Beckett |
| title |
Bis(triphenylphosphoranylidene)ammonium iodide |
| title_short |
Bis(triphenylphosphoranylidene)ammonium iodide |
| title_full |
Bis(triphenylphosphoranylidene)ammonium iodide |
| title_fullStr |
Bis(triphenylphosphoranylidene)ammonium iodide |
| title_full_unstemmed |
Bis(triphenylphosphoranylidene)ammonium iodide |
| title_sort |
bis(triphenylphosphoranylidene)ammonium iodide |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2010-02-01 |
| description |
The title compound, C36H30NP2+·I−, was obtained accidently from crystallization of a reaction mixture containing [(Ph3P)2N]OH and B(OH)3, which was contaminated with MeI. There are two independent [(Ph3P)2N]+ cations and two I− anions within the asymmetric unit. The central PNP angles are non-linear [137.6 (2) and 134.4 (2)°] and the phenyl substituents on P centres adopt different conformations within these two cations. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536810000267 |
| work_keys_str_mv |
AT michaelabeckett bistriphenylphosphoranylideneammoniumiodide AT peternhorton bistriphenylphosphoranylideneammoniumiodide AT michaelbhursthouse bistriphenylphosphoranylideneammoniumiodide AT jamesltimmis bistriphenylphosphoranylideneammoniumiodide |
| _version_ |
1724977476317216768 |