Transient and intermediate carbocations in ruthenium tetroxide oxidation of saturated rings

Transient and intermediate carbocations in ruthenium tetroxide oxidation of saturated rings

The ruthenium tetroxide-mediated oxidation of cyclopentane, tetrahydrofuran, tetrahydrothiophene and N-substituted pyrrolidines has been studied computationally by DFT and topological (analysis of the electron localization function, ELF) methods. In agreement with experimental observations and previ...

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Bibliographic Details
Main Authors: Manuel Pedrón, Laura Legnani, Maria-Assunta Chiacchio, Pierluigi Caramella, Tomás Tejero, Pedro Merino
Format: Article
Language:English
Published: Beilstein-Institut 2019-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
alkanes
carbocations
DFT
oxidations
ruthenium tetroxide
Online Access:https://doi.org/10.3762/bjoc.15.158

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