(Nitrato-κ2O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I)

(Nitrato-κ2O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I)

In the mononuclear title compound, [Ag(NO3)(C6H6N2O)2], the AgI atom is located on a twofold rotation axis and the nitrate-chelated AgI atom is further coordinated by two aromatic N atoms of hydroxylamine ligands in a distorted tetrahedral geometry. In the crystal, the nitrate ion has 2 symmetry wit...

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Main Authors: Shan Gao, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2012-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812046107
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spelling doaj-336adb500312408b970c31e990c2e25b2020-11-24T21:28:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812m1542m154210.1107/S1600536812046107(Nitrato-κ2O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I)Shan GaoSeik Weng NgIn the mononuclear title compound, [Ag(NO3)(C6H6N2O)2], the AgI atom is located on a twofold rotation axis and the nitrate-chelated AgI atom is further coordinated by two aromatic N atoms of hydroxylamine ligands in a distorted tetrahedral geometry. In the crystal, the nitrate ion has 2 symmetry with the N atom and one O atom located on the twofold rotation axis, and is linked to hydroxy groups of the hydroxylamine ligands by O—H...O hydrogen bonds, generating a chain running along the b axis.http://scripts.iucr.org/cgi-bin/paper?S1600536812046107
collection DOAJ
language English
format Article
sources DOAJ
author Shan Gao
Seik Weng Ng
spellingShingle Shan Gao
Seik Weng Ng
(Nitrato-κ2O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I)
Acta Crystallographica Section E
author_facet Shan Gao
Seik Weng Ng
author_sort Shan Gao
title (Nitrato-κ2O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I)
title_short (Nitrato-κ2O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I)
title_full (Nitrato-κ2O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I)
title_fullStr (Nitrato-κ2O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I)
title_full_unstemmed (Nitrato-κ2O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I)
title_sort (nitrato-κ2o,o′)bis[(e)-n-(pyridin-4-ylmethylidene-κn)hydroxyamine]silver(i)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-12-01
description In the mononuclear title compound, [Ag(NO3)(C6H6N2O)2], the AgI atom is located on a twofold rotation axis and the nitrate-chelated AgI atom is further coordinated by two aromatic N atoms of hydroxylamine ligands in a distorted tetrahedral geometry. In the crystal, the nitrate ion has 2 symmetry with the N atom and one O atom located on the twofold rotation axis, and is linked to hydroxy groups of the hydroxylamine ligands by O—H...O hydrogen bonds, generating a chain running along the b axis.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812046107
work_keys_str_mv AT shangao nitratoamp9542ooamp8242bisenpyridin4ylmethylideneamp954nhydroxyaminesilveri
AT seikwengng nitratoamp9542ooamp8242bisenpyridin4ylmethylideneamp954nhydroxyaminesilveri
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