Thermal Analysis and SEM Microscopy Applied to Studying the Efficiency of Ionic Liquid Immobilization on Solid Supports

• Main Authors: Anna Sowińska, Magdalena Maciejewska, Laina Guo, Etienne Delebecq
• Format: Article
• Language: English
• Published: MDPI AG 2019-05-01
• Series: Materials
• Subjects: ionic liquids; solid supports; thermogravimetry; DSC; fillers; immobilization
• Online Access: https://www.mdpi.com/1996-1944/12/10/1579

Ionic liquids (ILs) are widely used in elastomer composites, primarily as vulcanization activators or accelerators, crosslinkers, conductive additives, or dispersing agents of fillers. The aim of this work was to study the efficiency of ionic liquid immobilization on filler surfaces using different techniques of thermal analysis and scanning electron microscopy (SEM). Ionic liquid, such as 1-decyl 3-methylimidazolium bromide (DmiBr) was grafted on the surface of silica, calcium oxide, and carbon black to improve the dispersion degree of their particles in the elastomeric matrix. Thermal analysis and SEM microscopy revealed a key role in determining the efficiency of the filler modification with ILs dissolved in acetone. Identifying the weight loss associated with thermal decomposition of DmiBr in modified fillers, allowed the calculation of the efficiency of their modification and compare the surface reactivity of studied fillers with DmiBr. Silica and carbon black exhibited high and comparable ability for interaction with ionic liquid. SEM images showed that particles of DmiBr-modified fillers were quite homogeneously dispersed in the elastomer matrix and exhibited good adhesion to the elastomer.