Anion Influence on Spin State in Two Novel Fe(III) Compounds: [Fe(5F-sal2333)]X

Anion Influence on Spin State in Two Novel Fe(III) Compounds: [Fe(5F-sal2333)]X

Structural and magnetic data on two iron (III) complexes with a hexadentate Schiff base chelating ligand and Cl− or BPh4− counterions are reported. In the solid state, the Cl− complex [Fe(5F-sal2333)]Cl, 1, is high spin between 5–300 K while the BPh4&minus...

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Bibliographic Details
Main Authors:	Sriram Sundaresan, Irina A. Kühne, Conor T. Kelly, Andrew Barker, Daniel Salley, Helge Müller-Bunz, Annie K. Powell, Grace G. Morgan
Format:	Article
Language:	English
Published:	MDPI AG 2018-12-01
Series:	Crystals
Subjects:	Fe(III) coordination complexes hexadentate ligand Schiff base spin crossover UV-Vis spectroscopy SQUID EPR spectroscopy
Online Access:	http://www.mdpi.com/2073-4352/9/1/19

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