2-(2,4-Difluorophenyl)-5-nitropyridine

2-(2,4-Difluorophenyl)-5-nitropyridine

In the title molecule, C11H6F2N2O2, the benzene and pyridine rings form a dihedral angle of 32.57 (6)°. The nitro group is tilted with respect to the pyridine ring by 12.26 (9)°. An intramolecular C—H...F hydrogen bond is present. I...

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Bibliographic Details
Main Authors: Feng Sun, Xuan Shen, Rui Zhao, Xin Wang, Dun-Ru Zhu
Format: Article
Language:English
Published: International Union of Crystallography 2012-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812024713
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spelling doaj-334ff850d3ba423682f9ba2721bfc7812020-11-25T01:58:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687o2001o200110.1107/S16005368120247132-(2,4-Difluorophenyl)-5-nitropyridineFeng SunXuan ShenRui ZhaoXin WangDun-Ru ZhuIn the title molecule, C11H6F2N2O2, the benzene and pyridine rings form a dihedral angle of 32.57 (6)°. The nitro group is tilted with respect to the pyridine ring by 12.26 (9)°. An intramolecular C—H...F hydrogen bond is present. In the crystal, molecules interact through π–π stacking interactions [centroid–centroid distances = 3.7457 (14) Å], forming columnar arrangements along the b axis. The crystal packing is further enforced by intermolecular C—H...O and C—H...N hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536812024713
collection DOAJ
language English
format Article
sources DOAJ
author Feng Sun
Xuan Shen
Rui Zhao
Xin Wang
Dun-Ru Zhu
spellingShingle Feng Sun
Xuan Shen
Rui Zhao
Xin Wang
Dun-Ru Zhu
2-(2,4-Difluorophenyl)-5-nitropyridine
Acta Crystallographica Section E
author_facet Feng Sun
Xuan Shen
Rui Zhao
Xin Wang
Dun-Ru Zhu
author_sort Feng Sun
title 2-(2,4-Difluorophenyl)-5-nitropyridine
title_short 2-(2,4-Difluorophenyl)-5-nitropyridine
title_full 2-(2,4-Difluorophenyl)-5-nitropyridine
title_fullStr 2-(2,4-Difluorophenyl)-5-nitropyridine
title_full_unstemmed 2-(2,4-Difluorophenyl)-5-nitropyridine
title_sort 2-(2,4-difluorophenyl)-5-nitropyridine
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-07-01
description In the title molecule, C11H6F2N2O2, the benzene and pyridine rings form a dihedral angle of 32.57 (6)°. The nitro group is tilted with respect to the pyridine ring by 12.26 (9)°. An intramolecular C—H...F hydrogen bond is present. In the crystal, molecules interact through π–π stacking interactions [centroid–centroid distances = 3.7457 (14) Å], forming columnar arrangements along the b axis. The crystal packing is further enforced by intermolecular C—H...O and C—H...N hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812024713
work_keys_str_mv AT fengsun 224difluorophenyl5nitropyridine
AT xuanshen 224difluorophenyl5nitropyridine
AT ruizhao 224difluorophenyl5nitropyridine
AT xinwang 224difluorophenyl5nitropyridine
AT dunruzhu 224difluorophenyl5nitropyridine
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